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Crystal-chemical role of malonate ions in the structure of coordination polymers

  • Structure of Matter and Quantum Chemistry
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Abstract

In the crystal structures of the malonate-containing compounds of d- or f-metals, the C3H2O 2−4 anions were found to exhibit 17 topologically different types of coordination to the metal atoms A, playing the role of mono-, bi-, tri-, or tetradentate ligands and forming one to seven O-A bonds. The C-C-C bond angle in the malonate ions changed from 103° to 126° and depended linearly on the dihedral angle (φCOO) between the planes of the two carboxyl groups of the anion. At φCOO < 60°, the malonate ions in the crystal structures always form six-membered metallocycles with d- or f-metal atoms, while at φCOO > 67°, they can form only four-membered metallocycles. The factors that influence the conformation of malonate ions in the structures of coordination polymers were discussed.

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Authors and Affiliations

  1. Samara State University, Samara, Russia

    V. N. Serezhkin, Ya. A. Medvedkov, L. B. Serezhkina & D. V. Pushkin

Authors
  1. V. N. Serezhkin
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  2. Ya. A. Medvedkov
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  3. L. B. Serezhkina
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  4. D. V. Pushkin
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Correspondence to V. N. Serezhkin.

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Original Russian Text © V.N. Serezhkin, Ya.A. Medvedkov, L.B. Serezhkina, D.V. Pushkin, 2015, published in Zhurnal Fizicheskoi Khimii, 2015, Vol. 89, No. 6, pp. 978–988.

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Serezhkin, V.N., Medvedkov, Y.A., Serezhkina, L.B. et al. Crystal-chemical role of malonate ions in the structure of coordination polymers. Russ. J. Phys. Chem. 89, 1018–1027 (2015). https://doi.org/10.1134/S0036024415060254

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  • DOI: https://doi.org/10.1134/S0036024415060254

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