Abstract
Alkyl-substituted (methyl, ethyl, diethyl) malonate ions (Rmal2−) are found to display 13 topologically different types of coordination with respect to d- or f-metals A. The factors that cause Rmal2− ions to choose one possible coordination are discussed; valence angle C—C—C in a malonate ion lies within 102°–119° range and depends linearly on the dihedral angle between the planes of two carboxyl groups. When coordinated with metal atom A, alkyl-substituted malonate ions are found to produce six-membered metallocycles of bath conformation. It is established that increasing the volume of R substituents in Rmal2− ions strengthens the repulsion among carboxyl groups and alkyl substituents and reduces the C—C—C angle.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
C. Dey, T. Kundu, B. P. Biswal, et al., Acta Crystallogr. 70, 3 (2014).
B.-H. Ye, M.-L. Tong, and X.-M. Chen, Coord. Chem. Rev. 249, 545 (2005).
L. A. Borkowski and C. L. Cahill, Cryst. Growth Des. 6, 2241 (2006).
R. J. Kuppler, D. J. Timmons, Qian-Rong Fang, et al., Coord. Chem. Rev. 253, 3042 (2009).
A. D. Pomogailo and G. I. Dzhardimalieva, Monomeric and Polymeric Metal Carboxylates (Fizmatlit, Moscow, 2009) [in Russian].
S. Qiu and G. Zhu, Coord. Chem. Rev. 253, 2891 (2009).
A. T. Kerr and C. L. Cahill, Cryst. Growth Des. 11, 5634 (2011).
M. P. Yutkin, D. N. Dybtsev, and V. P. Fedin, Russ. Chem. Rev. 80, 1009 (2011).
G. Férey, Chem. Soc. Rev. 37, 191 (2008).
V. N. Serezhkin, Ya. A. Medvedkov, L. B. Serezhkina, and D. V. Pushkin, Russ. J. Phys. Chem. A 89, 1018 (2015).
J. M. Herbert and J. V. Ortiz, J. Phys. Chem. A 104, 11786 (2000).
D. W. Deerfield II and L. G. Pedersen, J. Mol. Struct. (THEOCHEM) 368, 163 (1996).
D. Ajó, I. Fragalá, G. Grannozi, and E. Tondello, J. Mol. Struct. 38, 245 (1977).
M. Déniz, I. Hernández-Rodríguez, J. Pasán, et al., Cryst. Eng. Commun., No. 13, 2766 (2014).
Y. Zhang, D. Collison, F. R. Livens, et al., Polyhedron 21, 81 (2002).
Y. Zhang, D. Collison, F. R. Livens, et al., Polyhedron 21, 69 (2002).
P. Manochitra, N. Manikandan, S. Murugavel, et al., Acta Crystallogr. E 68, m884 (2012).
S. Pérez-Yáñez, O. Castillo, J. Cepeda, et al., Eur. J. Inorg. Chem. 26, 3889 (2009).
M. Déniz, J. Pasán, J. Ferrando-Soria, et al., Inorg. Chem. 50, 10765 (2011).
M.-L. Guo and C.-H. Guo, Acta Crystallogr. C 65, m266 (2009).
Y. Zhang, D. Collison, F. R. Livens, et al., Polyhedron 14, 1757 (2000).
E. N. Zorina, N. V. Zauzolkova, A. A. Sidorov, et al., Inorg. Chim. Acta 396, 108 (2013).
G. A. Farnum, J. H. Nettleman, and R. L. LaDuca, Cryst. Eng. Comm, No. 12, 888 (2010).
Cambridge Structural Database System, Version 5.35 (Crystallogr. Data Centre, Cambridge, 2014).
V. N. Serezhkin, L. B. Serezhkina, A. P. Shevchenko, and D. V. Pushkin, Russ. J. Phys. Chem. A 79, 918 (2005).
V. N. Serezhkin, Yu. N. Mikhailov, and Yu. A. Buslaev, Russ. J. Inorg. Chem. 42, 1871 (1997).
M.-L. Guo and Y.-N. Zhao, Acta Crystallogr. C 62, m563 (2006).
J. Pasán, J. Sanchiz, L. Canadillas-Delgado, et al., Polyhedron 28, 1802 (2009).
D. Cremer and J. A. Pople, J. Am. Chem. Soc. 96, 1354 (1975).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © Ya.A. Medvedkov, L.B. Serezhkina, V.N. Serezhkin, 2016, published in Zhurnal Fizicheskoi Khimii, 2016, Vol. 90, No. 4, pp. 576–582.
Rights and permissions
About this article
Cite this article
Medvedkov, Y.A., Serezhkina, L.B. & Serezhkin, V.N. The Crystal-Chemical Role of Alkylmalonate Ions in the Structure of Coordination Polymers. Russ. J. Phys. Chem. 90, 803–808 (2016). https://doi.org/10.1134/S0036024416040191
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0036024416040191