Skip to main content
Log in

Transformation of wood during ozonization in the presence of hydrogen peroxide

  • Chemical Kinetics and Catalysis
  • Published:
Russian Journal of Physical Chemistry A Aims and scope Submit manuscript

Abstract

Samples of ozonized aspen wood pretreated with hydrogen peroxide solutions of various concentrations are investigated by UV diffuse reflectance spectroscopy, IR spectroscopy, and X-ray structural analysis. The general course of wood transformation under the action of the O3/H2O2 system is associated with the destruction of lignin and oxidation of carbohydrates, raising the fraction of the crystalline phase in a lignocarbohydrate material. The possibility of varying the depth of the chemical and structural transformation of the substrate upon changing the hydrogen peroxide concentration in the O3/H2O2 system is demonstrated.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. S. A. Kuznetsova, Extended Abstract of Doctoral Dissertation in Chemistry (Krasnoyarsk, 2005).

  2. V. G. Danilov, O. V. Yatsenkova, S. A. Kuznetsova, and B. N. Kuznetsov, RF Patent No. 2251602, Byull. No. 13 (2005).

    Google Scholar 

  3. K. G. Bogolitsyn, V. V. Lunin, D. S. Kosyakov, et al., Physical Chemistry of Lignin, Ed. by K. G. Bogolitsyn and V. V. Lunin (Arkhang. Gos. Tekh. Univ., Arkhangelsk, 2009) [in Russian].

  4. R. Sun, J. Tomkinson, F. C. Mao, and X. F. Sun, J. Appl. Polym. Sci. 79, 719 (2000).

    Article  Google Scholar 

  5. V. A. Demin, V. V. Shereshovets, and Yu. B. Monakov, Russ. Chem. Rev. 68, 937 (1999).

    Article  CAS  Google Scholar 

  6. M. B. Roncero, J. F. Colom, and T. Vidal, Carbohydr. Polym. 51, 243 (2003).

    Article  CAS  Google Scholar 

  7. M. B. Roncero, J. F. Colom, and T. Vidal, Carbohydr. Polym. 51, 411 (2003).

    Article  Google Scholar 

  8. N. A. Mamleeva, S. A. Autlov, N. G. Bazarnova, and V. V. Lunin, RF Patent No. 2413045, Byull. No. 6 (2009).

    Google Scholar 

  9. N. A. Mamleeva, S. A. Autlov, N. G. Bazarnova, and V. V. Lunin, Pure Appl. Chem. 81, 2081 (2009).

    Article  CAS  Google Scholar 

  10. C. L. Filho, H. U. Suess, M. R. Silva, et al., Congresso Internac. Cellulose Papel. San Paulo, ABTCP-TAPPI (2003).

    Google Scholar 

  11. N. A. Mamleeva, A. N. Kharlanov, A. V. Fionov, and V. V. Lunin, Russ. J. Phys. Chem. A 85, 1729 (2011).

    Article  CAS  Google Scholar 

  12. N. A. Mamleeva, A. N. Kharlanov, and V. V. Lunin, Russ. J. Phys. Chem. A 87, 28 (2013).

    Article  CAS  Google Scholar 

  13. Vel. Karpel, N. Leitner, A.-L. Papailhou, J. P. Croue, J. Peyrot, and M. Dore, Ozone Sci. Eng. 16, 51 (1994).

    Google Scholar 

  14. J. Staehelin and J. Hoigne, Environ. Sci. Technol. 16, 676 (1982).

    Article  CAS  Google Scholar 

  15. A. V. Obolenskaya, Z. P. El’nitskaya, and A. A. Leonovich, Laboratory Works on Chemistry of Wood and Cellulose (Ekologiya, Moscow, 1991) [in Russian].

    Google Scholar 

  16. A. Smith, Applied IR Spectroscopy (Wiley, New York, 1979; Mir, Moscow, 1982).

    Google Scholar 

  17. N. G. Bazarnova and E. V. Karpova, Methods of Research of Wood and Its Derivatives, Ed. by N. G. Bazarnova (Alt. Gos. Univ., Barnaul, 2002) [in Russian].

  18. R. H. Marchessault, Pure Appl. Chem. 5, 107 (1962).

    Article  CAS  Google Scholar 

  19. L. A. Aleshina, S. V. Glazkova, L. A. Lugovskaya, et al., Khim. Rastit. Syr’ya, No. 1, 5 (2001).

    Google Scholar 

  20. S. V. Barishnikkov, V. I. Sharipov, A. M. Gigaev, et al., J. Siberian Federal Univ. Chem. 2(3), 120 (2010).

    Google Scholar 

  21. S. Park, J. O. Baker, M. E. Himmel, et al., Biotechnol. Biofuels 3, 10 (2010).

    Article  Google Scholar 

  22. M. Ya. Ieolovich and G. P. Veveris, Khim. Drev., No. 5, 72 (1987).

    Google Scholar 

  23. L. Segal, J. J. Creely, A. E. Martin, Jr., and C. M. Conrad, Tex. Res. J. 29, 786 (1962).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to N. A. Mamleeva.

Additional information

Original Russian Text © N.A. Mamleeva, G.E. Abrosimova, A.N. Kharlanov, V.V. Lunin, 2013, published in Zhurnal Fizicheskoi Khimii, 2013, Vol. 87, No. 7, pp. 1124–1130.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Mamleeva, N.A., Abrosimova, G.E., Kharlanov, A.N. et al. Transformation of wood during ozonization in the presence of hydrogen peroxide. Russ. J. Phys. Chem. 87, 1102–1107 (2013). https://doi.org/10.1134/S0036024413070200

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036024413070200

Keywords

Navigation