Skip to main content
SpringerLink
Log in

The mechanosorption of carbon dioxide by magnesium, calcium, and strontium metasilicates

  • Physical Chemistry of Surface Phenomena
  • Published:
Russian Journal of Physical Chemistry A Aims and scope Submit manuscript

Abstract

Processes that occurred in the mechanical activation of MSiO3 silicates (M = Mg, Ca, Sr) in a centrifugal planetary mill in the atmosphere of carbon dioxide (p(CO2) = 105 Pa) were comparatively studied. The interaction of carbon dioxide with silicates had the character of deep mechanosorption with massed penetration of gas molecules into the volume of particles and their “solution” in structurally disordered silicate matrices in the form of distorted CO 2−3 ions. No individual carbonate phases were formed. The absorbing ability of silicates with respect to carbon dioxide decreased in the series SrSiO3 > CaSiO3 > MgSiO3. The carbon dioxide mechanosorption coefficients K MS were calculated for Mg, Ca, and Sr silicates according to the earlier suggested kinetic model. A linear dependence of logK MS on Δr G o298 for the transformation of silicates into the corresponding carbonates was observed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. E. V. Kalinkina, A. M. Kalinkin, W. Forsling, and V. N. Makarov, Int. J. Miner. Process. 61, 273 (2001).

    Article  CAS  Google Scholar 

  2. A. M. Kalinkin, A. A. Politov, V. V. Boldyrev, et al., Dokl. Akad. Nauk 378, 233 (2001).

    CAS  Google Scholar 

  3. A. M. Kalinkin, Zh. Fiz. Khim. 82, 331 (2008) [Russ. J. Phys. Chem. A 82, 263 (2008)].

    Google Scholar 

  4. A. M. Kalinkin, E. V. Kalinkina, O. A. Zalkind, and T. I. Makarova, Kolloidn. Zh. 70, 39 (2008) [Colloid. J. 70, 33 (2008)].

    Google Scholar 

  5. G. Heinicke, Tribochemistry (Academ. Verlag, Berlin, 1984; Mir, Moscow, 1987).

    Google Scholar 

  6. G. S. Khodakov, Kolloidn. Zh. 56, 113 (1994).

    CAS  Google Scholar 

  7. P. Yu. Butyagin, Usp. Khim. 63, 1031 (1994).

    CAS  Google Scholar 

  8. E. G. Avvakumov, Mechanical Methods for Activating Chemical Processes (Nauka, Novosibirsk, 1986) [in Russian].

    Google Scholar 

  9. V. V. Boldyrev, Usp. Khim. 75, 203 (2006).

    Google Scholar 

  10. A. M. Kalinkin, E. V. Kalinkina, and O. A. Zalkind, Kolloidn. Zh. 71, 194 (2009) [Colloid. J. 71, 185 (2009)].

    Google Scholar 

  11. A. M. Kalinkin, Kolloidn. Zh. 71(2), 202 (2009) [Colloid. J. 71, 193 (2009)].

    Google Scholar 

  12. E. G. Avvakumov and V. A. Pushnyakova, Khim. Tekhnol., No. 5, 6 (2002).

  13. J. V. Smith, Acta Crystallogr. 12, 515 (1959).

    Article  CAS  Google Scholar 

  14. K. Machida, G. Adachi, J. Shiokawa, et al., Acta Crystallogr. B 38, 386 (1982).

    Article  Google Scholar 

  15. A. M. Dymov, Technical Analysis (Metallurgiya, Moscow, 1964) [in Russian].

    Google Scholar 

  16. I. I. Plyusnina, Infrared Spectra of Minerals (Mosc. Gos. Univ., Moscow, 1977) [in Russian].

    Google Scholar 

  17. A. M. Kalinkin, A. A. Politov, V. V. Boldyrev, et al., J. Mater. Synt. Proc. 10, 59 (2002).

    Google Scholar 

  18. A. M. Kalinkin, E. V. Kalinkina, and T. N. Vasil’eva, Kolloidn. Zh. 66, 190 (2004) [Colloid. J. 66, 160 (2004)].

    Google Scholar 

  19. A. M. Kalinkin, E. V. Kalinkina, O. A. Zalkind, and T. I. Makarova, Neorg. Mater. 41, 1218 (2005) [Inorg. Mater. 41, 1073 (2005)].

    Article  Google Scholar 

  20. A. S. Povarennykh, Hardness of Minerals (Akad. Nauk USSR, Kiev, 1963) [in Russian].

    Google Scholar 

  21. P. Yu. Butyagin, Kolloidn. Zh. 59, 460 (1997) [Colloid. J. 59, 425 (1997)].

    Google Scholar 

  22. A. L. McLellan and H. F. Harnsberger, Thin Solid Films 23, 577 (1967).

    Google Scholar 

  23. A. N. Streletskii, P. Yu. Butyagin, and A. V. Leonov, Kolloidn. Zh. 58, 248 (1996) [Colloid. J. 58, 238 (1996)].

    Google Scholar 

  24. A. N. Streletskii and P. Yu. Butyagin, Kinet. Katal. 21, 770 (1980).

    CAS  Google Scholar 

  25. L. S. Vasil’ev and S. F. Lomaeva, Kolloidn. Zh. 65, 697 (2003) [Colloid. J. 65, 639 (2003)].

    Google Scholar 

  26. P. Yu. Butyagin, Kolloidn. Zh. 65, 706 (2003) [Colloid. J. 65, 648 (2003)].

    Google Scholar 

  27. H. Yokogawa, J. Nat. Chem. Lab. Ind. 83(Spec. Iss.), 27 (1988).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials, Kola Scientific Center, Russian Academy of Sciences, Apatity, Murmanskaya oblast, Russia

    A. M. Kalinkin & E. V. Kalinkina

Authors
  1. A. M. Kalinkin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. E. V. Kalinkina
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. M. Kalinkin.

Additional information

Original Russian Text © A.M. Kalinkin, E.V. Kalinkina, 2010, published in Zhurnal Fizicheskoi Khimii, 2010, Vol. 84, No. 9, pp. 1737–1743.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kalinkin, A.M., Kalinkina, E.V. The mechanosorption of carbon dioxide by magnesium, calcium, and strontium metasilicates. Russ. J. Phys. Chem. 84, 1585–1591 (2010). https://doi.org/10.1134/S0036024410090256

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036024410090256

Keywords

Search

Navigation