Abstract
Heat capacities of solutions of alkali metal iodides (MeI) in N-methylpyrrolidone (MP)-water mixed solvent were measured over the range of compositions. The influence of the composition of the mixed solvent on the heat capacity of MeI-MP-H2O ternary systems is discussed. Standard partial molar heat capacities \( \bar C_{p_2 }^o \) (MeI) in the MP-water mixed solvent at 298.15 K are calculated.
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V. A. Vasilev and A. N. Novikov, Zh. Fiz. Khim. 67, 1387 (1993).
A. N. Novikov and V. A. Vasilev, Zh. Fiz. Khim. 80, 598 (2006) [Russ. J. Phys. Chem. A 80, 505 (2006)].
A. N. Novikov, V. A. Vasilev, and O. F. Lenina, Zh. Fiz. Khim. 81, 1947 (2007) [Russ. J. Phys. Chem. A 81, 1743 (2007)].
A. N. Novikov and V. A. Vasilev, Zh. Fiz. Khim. 82, 1217 (2008) [Russ. J. Phys. Chem. A 82, 1071 (2008)].
A. N. Novikov, O. F. Lenina, and V. A. Vasilev, Zh. Fiz. Khim. 82, 1270 (2008) [Russ. J. Phys. Chem. A 82, 1121 (2008)].
P. Assarsson and F. R. Eirich, J. Phys. Chem. 72, 2710 (1968).
L. D. Afanasenko, N. L. Yarym-Agaev, E. O. Tsybul’skii, et al., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol. 27, 184 (1984).
G. Guarino, O. Ortona, R. Sartorlo, et al., J. Chem. Eng. Data 30, 366 (1985).
N. V. Ryabtseva, V. Ya. Rudin, and V. P. Kalinichenko, Zh. Prikl. Khim. 58, 1138 (1985).
V. A. Vasilev and A. N. Novikov, Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol. 32(12), 53 (1989).
A. M. Zaichikov, Y. G. Bushuev, and G. A. Krestov, J. Therm. Analysis 45, 687 (1995).
T. J. Carver, M. G. B. Drew, and P. M. Rodger, Phys. Chem. Chem. Phys. 1, 1807 (1999).
L. D. Afanasenko, N. L. Yarym-Agaev, and V. M. Bilobrov, Ukr. Khim. Zh. 53, 153 (1987).
B. V. Mikhailin, A. F. Vorob’ev, and V. A. Vasilev, Zh. Fiz. Khim. 56, 1937 (1982).
K. P. Mishchenko and G. M. Poltoratskii, Thermodynamics and Structure of Aqueous and Nonaqueous Solutions of Electrolytes (Khimiya, Leningrad, 1976) [in Russian].
V. A. Vasilev, Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol. 22, 1458 (1979).
V. A. Vasilev, Zh. Fiz. Khim. 54, 796 (1980).
V. A. Latysheva, Saline Aqueous Solutions: A Systematic Approach (SPb. Univ., St.-Petersburg, 1998) [in Russian].
V. A. Vasilev, Doctoral Dissertation in Chemistry (MKhTI, Moscow, 1980).
Yu. P. Syrnikov, Zh. Strukt. Khim. 12, 1082 (1971).
D. Eizenberg and V. Kautsman, Structure and Properties of Water (Gidrometeoizdat, Leningrad, 1975) [in Russian].
V. P. Belousov and M. Y. Panov, Therodynamic Properties of Aqueous Solutions of Organic Substances (CRC, Boca Raton, London, Tokyo, 1994).
Y. Koga, J. Phys. Chem. 100, 5172 (1996).
Y. Koga, Netsu Sokutei 30(2), 54 (2003).
A. M. Zaichikov, Zh. Obshch. Khim. 76, 660 (2006) [Russ. J. Gen. Chem. 76, 626 (2006)].
T. D. Kuanyshbaev, A. S. Monaenkova, and A. F. Vorob’ev, Zh. Fiz. Khim. 63, 2847 (1989).
V. N. Markov, V. A. Sharnin, V. A. Shormanov, and G. A. Krestov, Zh. Fiz. Khim. 66, 1192 (1992).
T. I. Chankina and V. I. Parfenyuk, Zh. Fiz. Khim. 78, 1592 (2004) [Russ. J. Phys. Chem. A 78, 1396 (2004)].
A. Ben-Naim, Pure Appl. Chem. 62, 25 (1990).
Problems of Solution Chemistry. Ionic Solvation, Ed. by G. A. Krestov, N. P. Novoselov, I. S. Perelygin, et al. (Nauka, Moscow, 1987) [in Russian].
Achievements and Problems of the Theory of Solvation: Structurally-Thermodynamic Aspects, Ed. by A. M. Kutepov (Nauka, Moscow, 1998) [in Russian].
G. A. Krestov, V. I. Vinogradov, Yu. M. Kessler, et al., Modern Problems of Solution Chemistry (Nauka, Moscow, 1986) [in Russian].
Y. Marcus, Ion S?lvation (Wiley, Chichester, 1985).
N. G. Manin, I. B. Kurbanov, and V. P. Korolev, Zh. Fiz. Khim. 73, 470 (1999) [Russ. J. Phys. Chem. A 73, 400 (1999)].
A. V. Pishchenkov, V. A. Sharnin, V. A. Shormanov, and G. A. Krestov, Zh. Fiz. Khim. 58, 2475 (1984).
B. V. Mikhailin, Candidate’s Dissertation in Chemistry (MKhTI, Moscow, 1983).
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Original Russian Text © A.N. Novikov, 2010, published in Zhurnal Fizicheskoi Khimii, 2010, Vol. 84, No. 9, pp. 1670–1675.
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Novikov, A.N. Concentration dependences of the heat capacity of solutions of alkali metal iodides in N-methylpyrrolidone-water mixed solvent at 298.15 K. Russ. J. Phys. Chem. 84, 1520–1525 (2010). https://doi.org/10.1134/S003602441009013X
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DOI: https://doi.org/10.1134/S003602441009013X