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The rules governing hydrogen combustion close to the lower ignition limit in the kinetic region of chain termination

  • Chemical Kinetics and Catalysis
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Abstract

The kinetic scheme of hydrogen combustion near the lower self-ignition limit in the kinetic region can be augmented by the reactions of bimolecular nonlinear termination O + OH → H + O2 and heterogeneous propagation of chains with the participation of adsorbed hydrogen atoms Hs. The literature data on the experimental determination of the probability of hydrogen atom trapping by the surface of quartz were analyzed.

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References

  1. L. V. Karmilova, A. B. Nalbandyan, and N. N. Semenov, Zh. Fiz. Khim. 32, 1193–1204 (1958).

    CAS  Google Scholar 

  2. N. N. Semenov, On Some Problems of Chemical Kinetics and Reaction Ability (Akad. Nauk SSSR, Moscow, 1958), p. 686 [in Russian].

    Google Scholar 

  3. N. N. Semenov, Development of Chain Reactions and Thermal Explosion Theory (Znanie, Moscow, 1969) [in Russian].

    Google Scholar 

  4. V. N. Kondrat’ev and E. E. Nikitin, Kinetics of Gas Phase Reactions (Nauka, Moscow, 1973) [in Russian].

    Google Scholar 

  5. N. M. Emanuel’ and D. G. Knorre, Course of Chemical Kinetics (Vysshaya Shkola, Moscow, 1984) [in Russian].

    Google Scholar 

  6. E. N. Aleksandrov, Fiz. Goreniya Vzryva 42(2), 10 (2006).

    CAS  Google Scholar 

  7. E. N. Aleksandrov, N. M. Kuznetsov, and S. N. Kozlov, Fiz. Goreniya Vzryva 43(5), 44 (2007).

    CAS  Google Scholar 

  8. A. B. Nalbandyan and V. V. Voevodskii, Mechanism of Oxydizing and Burning of Hydrogen (Akad. Nauk SSSR, Moscow, 1948) [in Russian].

    Google Scholar 

  9. N. M. Rubtsov, G. I. Tsvetkov, and V. I. Chernysh, Kinet. Katal. 49(3), 1 (2008) [Kinet. Catal. 49, 344 (2008)].

    Article  Google Scholar 

  10. E. N. Aleksandrov and V. V. Azatyan, Dokl. Akad. Nauk SSSR 210, 1358 (1973).

    CAS  Google Scholar 

  11. W. V. Smith, J. Chem. Phys 11, 110 (1943).

    Article  CAS  Google Scholar 

  12. V. V. Voevodskii and G. K. Lavrovskaya, Zh. Fiz. Khim. 25, 1050 (1951).

    Google Scholar 

  13. M. Treen, K. R. Lennings, J. W. Linnet, and D. Schofield, Trans. Farad. Soc. 55, 2152 (1959).

    Article  Google Scholar 

  14. I. N. Pospelova and I. A. Myasnikov, Dokl. Akad. Nauk SSSR 190, 390 (1970).

    CAS  Google Scholar 

  15. V. A. Lavrenko, A. A. Chekhovskoi, and V. A. Tikush, Kinet. Katal. 15, 1072 (1974).

    CAS  Google Scholar 

  16. M. U. Kislyuk and O. V. Krylov, Kinet. Katal. 11, 1200 (1970).

    CAS  Google Scholar 

  17. A. B. Nalbandyan and S. M. Shubina, Zh. Fiz. Khim. 20, 1249 (1946).

    CAS  Google Scholar 

  18. E. I. Semenov and V. V. Azatyan, in Combustion and Explosion, Collected Vol. (Nauka, Moscow, 1972), p. 625 [in Russian].

    Google Scholar 

  19. V. V. Azatyan, M. U. Kislyuk, I. I. Tret’yakov, and A. A. Shavard, Kinet. Katal. 21, 583 (1980).

    CAS  Google Scholar 

  20. V. V. Azatyan, R. G. Aivazyan, A. A. Kadushin, et al., Kinet. Katal. 27, 405 (1986).

    CAS  Google Scholar 

  21. V. P. Karpov, N. M. Rubtsov, O. T. Ryzhkov, et al., Khim. Fiz. 17(4), 73 (1998).

    CAS  Google Scholar 

  22. V. V. Azatyan, N. M. Rubtsov, G. I. Tsvetkov, and V. I. Chernysh, Zh. Fiz. Khim. 79, 402 (2005) [Russ. J. Phys. Chem. 79, 320 (2005)].

    Google Scholar 

  23. N. N. Semenov and V. V. Azatyan, in Proc. of the All-Union Symp. on Combustion (Nauka, Moscow, 1971), p. 258.

    Google Scholar 

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Authors and Affiliations

  1. Institute of Structural Macrokinetics and Materials Science Problems, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432, Russia

    N. M. Rubtsov, G. I. Tsvetkov & V. I. Chernysh

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  1. N. M. Rubtsov
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  2. G. I. Tsvetkov
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  3. V. I. Chernysh
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Correspondence to N. M. Rubtsov.

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Original Russian Text © N.M. Rubtsov, G.I. Tsvetkov, V.I. Chernysh, 2009, published in Zhurnal Fizicheskoi Khimii, 2009, Vol. 83, No. 10, pp. 1884–1887.

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Rubtsov, N.M., Tsvetkov, G.I. & Chernysh, V.I. The rules governing hydrogen combustion close to the lower ignition limit in the kinetic region of chain termination. Russ. J. Phys. Chem. 83, 1701–1703 (2009). https://doi.org/10.1134/S0036024409100124

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  • DOI: https://doi.org/10.1134/S0036024409100124

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