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Study of the Characteristics of Elementary Processes in a Chain Hydrogen Burning Reaction in Oxygen

  • Atoms, Molecules, Optics
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Abstract

The characteristics of possible chain explosive hydrogen burning reactions in an oxidizing medium are calculated on the potential energy surface. Specifically, reactions H2 + O2 → H2O + O, H2 + O2 → HO2 + H, and H2 + O2 → OH + OH are considered. Special attention is devoted to the production of a pair of fast highly reactive OH radicals. Because of the high activation threshold, this reaction is often excluded from the known kinetic scheme of hydrogen burning. However, a spread in estimates of kinetic characteristics and a disagreement between theoretical predictions with experimental results suggest that the kinetic scheme should be refined.

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Authors and Affiliations

  1. Troitsk Institute of Innovation and Thermonuclear Research, Troitsk, Moscow, 142190, Russia

    M. E. Bychkov, Yu. V. Petrushevich & A. N. Starostin

Authors
  1. M. E. Bychkov
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  2. Yu. V. Petrushevich
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  3. A. N. Starostin
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Correspondence to M. E. Bychkov.

Additional information

Original Russian Text © M.E. Bychkov, Yu.V. Petrushevich, A.N. Starostin, 2017, published in Zhurnal Eksperimental’noi i Teoreticheskoi Fiziki, 2017, Vol. 152, No. 6, pp. 1204–1212.

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Bychkov, M.E., Petrushevich, Y.V. & Starostin, A.N. Study of the Characteristics of Elementary Processes in a Chain Hydrogen Burning Reaction in Oxygen. J. Exp. Theor. Phys. 125, 1026–1033 (2017). https://doi.org/10.1134/S1063776117120019

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  • DOI: https://doi.org/10.1134/S1063776117120019

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