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The dielectric properties of polyatomic alcohols: Asymmetric dispersion in butanediols

  • Chemical Thermodynamics and Thermochemistry
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Abstract

Static permittivity ɛs, permittivity ɛ′, and dielectric loss ɛ″ were measured for 1,3-, 1,4-, and 2,3-butanediols over the frequency and temperature ranges 1 MHz-36 GHz and 293–423 K. These equilibrium properties of butanediols were analyzed using the Onsager-Kirkwood-Fröhlich theory. The correlation factor g over the temperature range was calculated. The experimental permittivity ɛ′ and dielectric loss ɛ″ values were described by the Davidson-Cole equation. The relaxation times τD-C and parameter β of their distribution were calculated.

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Authors and Affiliations

  1. Faculty of Chemistry, Moscow State University, Moscow, Russia

    V. I. Zhuravlev, N. V. Lifanova & T. M. Usacheva

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  1. V. I. Zhuravlev
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  2. N. V. Lifanova
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  3. T. M. Usacheva
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Correspondence to V. I. Zhuravlev.

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Original Russian Text © V.I. Zhuravlev, N.V. Lifanova, T.M. Usacheva, 2009, published in Zhurnal Fizicheskoi Khimii, 2009, Vol. 83, No. 2, pp. 213–219.

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Zhuravlev, V.I., Lifanova, N.V. & Usacheva, T.M. The dielectric properties of polyatomic alcohols: Asymmetric dispersion in butanediols. Russ. J. Phys. Chem. 83, 151–157 (2009). https://doi.org/10.1134/S0036024409020022

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  • DOI: https://doi.org/10.1134/S0036024409020022

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