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Dielectric properties of multiatomic alcohols: 1,3-butanediol

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Abstract

The dielectric spectra of 1,3-butanediol in the temperature range of 298–423 K are analyzed using a variety of theoretical approaches. It is shown that the dielectric spectra of 1,3-butanediol are described by the Davidson–Cole equation. Conclusions as to possible mechanisms of dispersion are drawn using the Debye theory. The relaxation times of 1,3-butanediol, calculated in different ways, are compared. The dipole moments of clusters are calculated for the first time using the Dissado–Hill cluster model.

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Authors and Affiliations

  1. Department of Chemistry, Moscow State University, Moscow, 119991, Russia

    V. I. Zhuravlev

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  1. V. I. Zhuravlev
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Correspondence to V. I. Zhuravlev.

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Original Russian Text © V.I. Zhuravlev, 2016, published in Zhurnal Fizicheskoi Khimii, 2016, Vol. 90, No. 10, pp. 1484–1490.

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Zhuravlev, V.I. Dielectric properties of multiatomic alcohols: 1,3-butanediol. Russ. J. Phys. Chem. 90, 1965–1971 (2016). https://doi.org/10.1134/S0036024416100332

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  • DOI: https://doi.org/10.1134/S0036024416100332

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