Abstract
The kinetics, thermodynamics, and mechanisms of two catastrophic copper oxidation stages, fast and superfast, are considered for the example of the Cu-Bi2O3 system, whose behavior most completely corresponds to that of other systems. The fast stage was shown to involve the formation of a liquid-channel grain boundary structure in the protective oxide layer, and the superfast stage, the solution of the protective oxide layer.
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Belousov, V.V. The “catastrophic” oxidation of metals. Russ. J. Phys. Chem. 82, 2243–2249 (2008). https://doi.org/10.1134/S0036024408130153
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DOI: https://doi.org/10.1134/S0036024408130153