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Mechanochemical synthesis of nanosized europium nitrate with 1,10-phenanthroline

  • Physical Chemistry of Nanotechnologies
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Abstract

Mechanochemically synthesized europium nitrate with 1,10-phenanthroline (Phen) is formed into globules with sizes of 100–300 nm, which are assembled into larger globular aggregates or packed into layers. The increasing mechanical activation time induces sintering, generating porous aggregates with micro-and nanopores. Eu2+ paramagnetic centers, detectable by ESR, are generated by mechanical grinding. Possibly, they are positioned on the surfaces of nanoglobules. The complex Eu(NO3)3 · 2Phen synthesized conventionally from aqueous ethanol consists of needle-shaped microcrystallites. They do not give rise to ESR spectra.

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References

  1. V. V. Boldyrev and E. G. Avvakumov, Usp. Khim. 40, 1836 (1971).

    Google Scholar 

  2. J. R. Sachleben, E. W. Wooten, L. Emsley, et al., Chem. Phys. Lett. 198(5), 431 (1992).

    Article  CAS  Google Scholar 

  3. B. P. Sobolev, The Rare Earth Trifluorides, Part 2: Introduction to Materials Science of Multicomponent Metal Fluoride Crystals (Institute d’Estudis Catalans, Barcelona, 2001).

    Google Scholar 

  4. B. P. Sobolev, A. M. Golubev, and P. Herrero, Kristallografiya 48(1), 148 (2003) [Crystallogr. Rep. 48 (1), 141 (2003)].

    Google Scholar 

  5. G. S. Khodakov, Physics of Grinding (Nauka, Moscow, 1972) [in Russian].

    Google Scholar 

  6. B. P. Sobolev, V. I. Sviridov, V. I. Fadeeva, et al., Kristallografiya 50(3), 524 (2005) [Crystallogr. Rep. 50 (3), 478 (2005)].

    Google Scholar 

  7. USSR Inventor’s Certificate No. 975068, Byull. Izobret., No. 43 (1982).

  8. I. V. Kalinovskaya and V. E. Karasev, Zh. Neorg. Khim. 38(2), 288 (1993).

    CAS  Google Scholar 

  9. I. V. Kalinovskaya and V. E. Karasev, Zh. Neorg. Khim. 45(9), 1488 (2000) [Russ. J. Inorg. Chem. 45 (9), 1360 (2000)].

    CAS  Google Scholar 

  10. F. A. Cotton and G. Wilkinson, Advanced Inorganic Chemistry (Wiley, New York, 1972).

    Google Scholar 

  11. Y. G. Klyavas, ESR Spectroscopy of Irregular Solids (Riga, Zinatne, 1988).

    Google Scholar 

  12. I. V. Kalinovskaya, A. N. Zadorozhnaya, V. G. Kuryavyi, and V. E. Karasev, Zh. Fiz. Khim. 81(7), 1302 (2007) [Russ. J. Phys. Chem. A 81 (7), 1147 (2007)].

    Google Scholar 

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Authors and Affiliations

  1. Institute of Chemistry, Far East Division, Russian Academy of Sciences, pr. Stoletiya Vladivostoka 159, Vladivostok, 690022, Russia

    I. V. Kalinovskaya, V. G. Kuryavyi, P. P. Safronov & V. E. Karasev

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  1. I. V. Kalinovskaya
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  2. V. G. Kuryavyi
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  3. P. P. Safronov
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  4. V. E. Karasev
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Correspondence to I. V. Kalinovskaya.

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Kalinovskaya, I.V., Kuryavyi, V.G., Safronov, P.P. et al. Mechanochemical synthesis of nanosized europium nitrate with 1,10-phenanthroline. Russ. J. Phys. Chem. 82, 2173–2175 (2008). https://doi.org/10.1134/S0036024408130037

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  • DOI: https://doi.org/10.1134/S0036024408130037

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