Abstract
Powdered nanocrystalline europium orthoferrite was synthesized by the glycine-nitrate combustion method, and specific features of its formation were studied in relation to the redox composition of the starting reaction mixture. The products of glycine-nitrate combustion were characterized by X-ray fluorescence microanalysis, X-ray diffraction analysis, scanning electron microscopy, and helium pycnometry. It was found that, depending on the glycine-nitrate ratio, EuFeO3 nanopowders with average crystallite size of 28 ± 3 to 46 ± 5 nm can be obtained. The crystallites form under the given conditions porous micrometer-size agglomerates with developed surface. Their morphology and characteristic size vary with the redox composition of the reaction mixture.
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Original Russian Text © K.D. Martinson, I.S. Kondrashkova, V.I. Popkov, 2017, published in Zhurnal Prikladnoi Khimii, 2017, Vol. 90, No. 8, pp. 980−985.
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Martinson, K.D., Kondrashkova, I.S. & Popkov, V.I. Synthesis of EuFeO3 nanocrystals by glycine-nitrate combustion method. Russ J Appl Chem 90, 1214–1218 (2017). https://doi.org/10.1134/S1070427217080031
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DOI: https://doi.org/10.1134/S1070427217080031