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Concentration dependences of the critical temperatures of binary mixtures of nonaqueous components

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Abstract

The critical (liquid-vapor) temperatures were determined by the ampule method for 10 binary mixtures containing aliphatic alcohols, n-octane, n-decane, methyl ethyl ketone, benzene, and toluene in various combinations. The predictive potential of several calculation methods was considered. The methods using binary interaction parameters as functions of the ratio between the critical volumes of compounds were found to correctly describe experimental data.

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References

  1. R. Reid, J. M. Prausnitz, and T. Sherwood, The Properties of Gases and Liquids (McGraw-Hill, New York, 1977; Khimiya, Leningrad, 1982).

    Google Scholar 

  2. B. E. Poling, J. M. Prausnitz, and J. P. O’Connell, The Properties of Gases and Liquids (McGraw-Hill, New York, 2001).

    Google Scholar 

  3. J. Seo, J. Lee, and H. Kim, J. Chem. Eng. Data 48, 856 (2003).

    Article  CAS  Google Scholar 

  4. J. Liu, Z. Oin, G. Wang, et al., J. Chem. Eng. Data 48, 1610 (2003).

    Article  CAS  Google Scholar 

  5. T. W. de Loos, W. Poot, A. J. de Swaan, Fluid Phase Egulib. 42, 209 (1988).

    Article  Google Scholar 

  6. J. Seo, J. Lee, and H. Kim, Fluid Phase Egulib. 172, 211 (2000).

    Article  CAS  Google Scholar 

  7. J. Seo, J. Lee, and H. Kim, Fluid Phase Egulib. 182, 199 (2001).

    Article  CAS  Google Scholar 

  8. J. Seo, J. Lee, and H. Kim, J. Chem. Eng. Data 48, 856 (2003).

    Article  CAS  Google Scholar 

  9. Byung Chul Oh, J. Lee, Jungha Seo, and H. Kim, J. Chem. Eng. Data 49, 221 (2004).

    Article  CAS  Google Scholar 

  10. S. Jung, M. Shin, and H. Kim, J. Chem. Eng. Data 51, 656 (2006).

    Article  CAS  Google Scholar 

  11. S. Jung, M. Shin, H. Kim, et al., J. Chem. Eng. Data 50, 1520 (2005).

    Article  Google Scholar 

  12. D. W. Morton, M. W. Lui, and C. L. Young, J. Chem. Thermodyn. 35, 1737 (2003).

    Article  CAS  Google Scholar 

  13. D. R. Lide and H. V. Kehiaian, CRC Handbook of Thermophysical and Thermochemical Data (CRC, Boca Raton, 2000).

    Google Scholar 

  14. V. B. Kogan, V. M. Fridman, and V. V. Kafarov, Equilibrium between Liquid and Vapor (Nauka, Moscow, 1966) [in Russian].

    Google Scholar 

  15. J. Seo, J. Lee, and H. Kim, J. Chem. Eng. Data 47, 974 (2002).

    Article  CAS  Google Scholar 

  16. A. G. Nazmutdinov, V. S. Sarkisova, N. N. Vodenkova, et al., Neftekhimiya 46(6), 458 (2006) [Pet. Chem. 46 (6), 428 (2006)].

    CAS  Google Scholar 

  17. Y. Higashi, J. Chem. Eng. Data 42, 1269 (1997).

    Article  CAS  Google Scholar 

  18. Y. Uchida, M. Yasumoto, Y. Yamada, et al., J. Chem. Eng. Data 49, 1615 (2004).

    Article  CAS  Google Scholar 

  19. I. A. Nesterov, A. G. Nazmutdinov, V. S. Sarkisova, et al., Neftekhimiya 47(6), 466 (2007).

    CAS  Google Scholar 

  20. M. Gude and A. S. Teja, J. Chem. Eng. Data 40, 1025 (1995).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Samara State Technical University, Samara, Russia

    A. G. Nazmutdinov, E. V. Alekina & T. N. Nesterova

Authors
  1. A. G. Nazmutdinov
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  2. E. V. Alekina
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  3. T. N. Nesterova
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Correspondence to A. G. Nazmutdinov.

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Original Russian Text © A.G. Nazmutdinov, E.V. Alekina, T.N. Nesterova, 2008, published in Zhurnal Fizicheskoi Khimii, 2008, Vol. 82, No. 11, pp. 2068–2073.

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Nazmutdinov, A.G., Alekina, E.V. & Nesterova, T.N. Concentration dependences of the critical temperatures of binary mixtures of nonaqueous components. Russ. J. Phys. Chem. 82, 1857–1862 (2008). https://doi.org/10.1134/S0036024408110125

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  • DOI: https://doi.org/10.1134/S0036024408110125

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