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Electrooptical and electrochemical properties of an ionic conjugated polymer, poly(2-ethynylpyridinum-N-benzoylsulfonate)

  • The International Conference “Modern Physical Chemistry for Advanced Materials”
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Abstract

The electrooptical and electrochemical properties of a self-dopable ionic conjugated polyacetylene, poly(2-ethynylpyridinium-N-benzoylsulfonate) (PEPBS), were studied. The photoluminescence spectra of the polymer showed that the photoluminescence peak was located at 545 nm corresponding to the photon energy of 2.27 eV. The cyclic voltammograms of the polymer exhibited reversible electrochemical behaviors between the doped and undoped peaks. It was found from the dependence of the oxidation current density of the polymer on scan rate that the kinetics of the redox process was diffusion-controlled. The electrical conductivity (σ) of undoped PEPBS was 5.7 × 10−9 S/cm.

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Authors and Affiliations

  1. Polymer Chemistry Laboratory, College of Engineering, Kyungil University, Kyungsan, 712-701, Korea

    Yeong-Soon Gal

  2. Department of Chemistry Education, Pusan National University, Pusan, 609-735, Korea

    Sung-Ho Jin

  3. Department of Textile and Fashion Technology, Kyungil University, Kyungsan, 712-701, Korea

    Won-Chul Lee

  4. Department of Chemistry, Center for Nanotech. Res., The Catholic University, Bucheon, 420-743, Korea

    Jong-Wook Park

  5. Division of Image and Information Engineering, Pukyong National University, Pusan, 608-739, Korea

    Kwon Taek Lim

  6. School of Textiles, Yeungnam University, Gyungsan, 712-749, Korea

    Won Seok Lyoo

  7. Department of Chemistry, KAIST, Taejon, 305-701, Korea

    Sang Youl Kim

Authors
  1. Yeong-Soon Gal
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  2. Sung-Ho Jin
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  3. Won-Chul Lee
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  4. Jong-Wook Park
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  5. Kwon Taek Lim
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  6. Won Seok Lyoo
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  7. Sang Youl Kim
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Correspondence to Yeong-Soon Gal.

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The text was submitted by the authors in English.

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Gal, YS., Jin, SH., Lee, WC. et al. Electrooptical and electrochemical properties of an ionic conjugated polymer, poly(2-ethynylpyridinum-N-benzoylsulfonate). Russ. J. Phys. Chem. 82, 1447–1450 (2008). https://doi.org/10.1134/S0036024408090069

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  • DOI: https://doi.org/10.1134/S0036024408090069

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