Abstract
The reaction of ozone with chlorobenzene was studied over the temperature range 77–305 K. Ozone was found to oxidize chlorobenzene starting with 77 K to produce a complex mixture of ozonides and peroxides of various compositions. The products of the reaction between chlorobenzene and ozone formed over the temperature range 77–305 K were analyzed by IR Fourier transform spectroscopy.
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References
Lehrbuch der ökologischen Chemie: Grundlagen und Konzepte für die ökologische Beurteilung von Chemikalien, Ed. by F. Korte (G. Thieme, Stuttgart, 1992; Mir, Moscow, 1997).
T. V. Yagodovskaya, R. A. Gromov, A. V. Zosimov, and V. V. Lunin, Zh. Fiz. Khim. 73(5), 857 (1999) [Russ. J. Phys. Chem. 73 (5), 751 (1999)].
T. V. Yagodovskaya, S. V. Savilov, A. V. Zosimov, and V. V. Lunin, Zh. Fiz. Khim. 74(6), 1149 (2000) [Russ. J. Phys. Chem. 74 (6), 1028 (2000)].
V. D. Komissarov and I. N. Komisarova, Izv. Akad. Nauk SSSR, Ser. Khim., 677 (1973).
S. D. Razumovskii and G. E. Zaikov, Izv. Akad. Nauk SSSR, Ser. Khim., 2657 (1971).
P. S. Baley, S. Bath, F. Dobinson, et al., J. Org. Chem. 29, 697 (1964).
M. G. Sturrock, B. J. Cravy, and V. A. Wing, Can. J. Chem. 49, 3047 (1971).
P. S. Baley and J. E. Batterbee, J. Org. Chem. 29, 1400 (1964).
P. S. Baley, J. E. Batterbee, and A. G. Lane, J. Am. Chem. Soc. 90(4), 1027 (1968).
C. R. Noller and G. K. Kaneko, J. Am. Chem. Soc. 57, 2442 (1935).
V. A. Yakobi, Tr. Mosk. Khim.-Tekhnol. Inst. im. Mendeleeva, No. 103, 66 (1979).
V. A. Yakobi, Zh. Fiz. Khim. 66(4), 867 (1992).
A. V. Mamchur, G. A. Galstyan, and E. V. Potapenko, Neftekhimiya 42(4), 287 (2002) [Pet. Chem. 42 (4), 257 (2002)].
J. P. Wibaut and F. L. J. Sixma, Recl. Trav. Chim. Pays-Bas 71, 761 (1952).
M. K. Wilson and R. D. Ogg, J. Chem. Phys. 18(5), 766 (1950).
T. V. Yagodovskaya, L. I. Nekrasov, and N. P. Klimushina, Zh. Fiz. Khim., No. 4, 902 (1967).
T. V. Yagodovskaya, M. R. Khadzhi-Ogly, and L. I. Nekrasov, Zh. Fiz. Khim. 60(4), 922 (1986).
Technique of Organic Chemistry, Ed. by A. Weissberger, Vol. 9: Chemical Applications of Spectroscopy, Ed. by W. West (Interscience, New York, 1956; Inostrannaya Literatura, Moscow, 1959).
L. A. Kazitsyna and N. B. Kupletskaya, Application of UV, IR, NMR, and Mass Spectroscopy in Organic Chemistry (Mosk. Gos. Univ., Moscow, 1979) [in Russian].
A. D. Cross, An Introduction to Practical Infra-Red Spectroscopy (Butterworths, London, 1960; Inostrannaya Literatura, Moscow, 1961).
G. V. Yukhnevich, Infrared Spectroscopy of Water (Nauka, Moscow, 1973) [in Russian].
R. Criegee, Chimia 22, 392 (1968).
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Original Russian Text © T.A. Vysokikh, T.V. Yagodovskaya, S.V. Savilov, V.V. Lunin, 2007, published in Zhurnal Fizicheskoi Khimii, 2007, Vol. 81, No. 6, pp. 1010–1014.
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Vysokikh, T.A., Yagodovskaya, T.V., Savilov, S.V. et al. The interaction of ozone with chlorobenzene. Russ. J. Phys. Chem. 81, 878–882 (2007). https://doi.org/10.1134/S0036024407060088
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DOI: https://doi.org/10.1134/S0036024407060088