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Singlet oxygen in the heterogeneous catalytic oxidation of benzene

  • Chemical Kinetics and Catalysis
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Abstract

The partial oxidation of benzene on vanadium and molybdenum oxides and the participation of singlet oxygen in this reaction were studied. A correlation between the activity of the catalysts in the partial oxidation of benzene and their ability to generate singlet oxygen was observed. The character of the initiation of oxidative benzene transformations under the action of molecular singlet oxygen was analyzed.

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Authors and Affiliations

  1. Gubkin State University of Oil and Gas, Leninskii pr. 65, Moscow, 117917, Russia

    E. V. Boikov, M. V. Vishnetskaya, A. N. Emel’yanov, N. V. Shcherbakov & I. S. Tomskii

  2. Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina 4, Moscow, 117977, Russia

    Yu. N. Rufov

Authors
  1. E. V. Boikov
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  2. M. V. Vishnetskaya
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  3. A. N. Emel’yanov
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  4. Yu. N. Rufov
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  5. N. V. Shcherbakov
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  6. I. S. Tomskii
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Additional information

Original Russian Text © E.V. Boikov, M.V. Vishnetskaya, A.N. Emel’yanov, Yu.N. Rufov, N.V. Shcherbakov, I.S. Tomskii, 2007, published in Zhurnal Fizicheskoi Khimii, 2007, Vol. 81, No. 6, pp. 993–997.

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Boikov, E.V., Vishnetskaya, M.V., Emel’yanov, A.N. et al. Singlet oxygen in the heterogeneous catalytic oxidation of benzene. Russ. J. Phys. Chem. 81, 861–865 (2007). https://doi.org/10.1134/S0036024407060052

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  • DOI: https://doi.org/10.1134/S0036024407060052

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