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Reaction of acetaldehyde with hydrogen peroxide at low temperatures: IR spectra in xenon matrices and calculations of intermediates and transition states

  • Problems of Chemical Kinetics and Catalysis
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Abstract

The products of the reaction between acetaldehyde and hydrogen peroxide were studied by measuring their IR spectra. Density functional calculations were performed for intermediates and stable reaction products and for saddle points of elementary processes possible in this system. It was shown that two products could be formed at the first stage, the hydroperoxide molecule and CH3CO radical.

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Authors and Affiliations

  1. Faculty of Chemistry, Moscow State University, Leninskie gory, Moscow, 119992, Russia

    L. V. Serebrennikov & A. V. Golovkin

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  1. L. V. Serebrennikov
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  2. A. V. Golovkin
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Serebrennikov, L.V., Golovkin, A.V. Reaction of acetaldehyde with hydrogen peroxide at low temperatures: IR spectra in xenon matrices and calculations of intermediates and transition states. Russ. J. Phys. Chem. 80 (Suppl 1), S63–S71 (2006). https://doi.org/10.1134/S0036024406130115

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  • DOI: https://doi.org/10.1134/S0036024406130115

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