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In Situ Ligand Synthesis Afforded Two New Metal-Organic Compounds: Luminescent and Photocatalytic Properties

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Abstract

Presented here are two metal-organic frameworks, namely [Zn(L)(bbp)]n (1) and [Cu(L)(bix)0.5]n (2) (H2L = 2-[(2-carboxyphenyl)disulfanyl]benzoic acid, bpp = 1,3-bis(4-pyridyl)propane, bix = 1,4-bis(imidazole-1-ylmethyl)benzene), which are synthesized under hydrothermal conditions. During this process, the 2-sulfanylbenzoic acid in situ transformed into H2L via the formation of disulfide bond. X-ray diffraction revealed that compound 1 displays a 3-fold interpenetrated 3D framework with 4-connected bcu topology, and compound 2 shows a 2D layered structure based on paddle-wheel shaped dinuclear [Cu2(COO)4] subunits and represents a 4-conneceted sql topology. Luminescence test revealed that compound 1 may be served as a good blue luminescent material. Photocatalytic experiment indicated that compound 2 may be applied as a highly effective photocatalyst for the photodegradation of MB aqueous solution under UV light irradiation.

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Funding

This work was supported by the Foundation of Hebei Education Department (ZD2020193), and the Foundation of Hebei Education Department (ZD2022084).

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Authors and Affiliations

  1. University, City, Country Department of Environmental and Chemical Engineering, Hebei College of Industry and Technology, 0590091, Shijiazhuang, Hebei, China

    L.-D. Guo, Y.-Y. Liu, X.-R. Zuo, J. Yao, J.-R. Sun, D.-M. Xu, F.-P. Li & W.-H. Li

  2. Department of Radiation Oncology, The Fourth Hospital Attached to Hebei Medical University, 050011, Shijiazhuang, China

    X.-H. Zhao

Authors
  1. L.-D. Guo
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  2. X.-H. Zhao
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  3. Y.-Y. Liu
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  4. X.-R. Zuo
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  5. J. Yao
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  6. J.-R. Sun
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  7. D.-M. Xu
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  8. F.-P. Li
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  9. W.-H. Li
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Contributions

L.-D. Guo and X.-H. Zhao contributed equally to this work.

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Correspondence to W.-H. Li.

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Guo, LD., Zhao, XH., Liu, YY. et al. In Situ Ligand Synthesis Afforded Two New Metal-Organic Compounds: Luminescent and Photocatalytic Properties. Russ. J. Inorg. Chem. 67, 2140–2147 (2022). https://doi.org/10.1134/S0036023622700097

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  • DOI: https://doi.org/10.1134/S0036023622700097

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