Abstract
The SnTe–Sb2Te3–Te system was studied in the temperature range 300–400 K by X-ray powder diffraction and EMF measurements of (–) SnTe(s.)|liquid electrolyte, Sn2+|(Sn–Sb–Te) (s) (+) reversible concentration cells. An equilibrium solid phase diagram of the system was constructed. All telluride phases of the system, namely, ternary compounds SnSb2Te4 and SnSb4Te7 and SnTe-base (α) and Sb2Te3-base (β) solid solutions, were found to be tie-lined with tellurium. Equations for temperature-dependent EMF in β + Те, β + SnSb4Te7 + Те, SnSb4Te7 + SnSb2Te4 + Те, α + SnSb2Te4 + Те, and α + Те heterogeneous phase fields were derived from EMF measurements, and were used to calculate the partial thermodynamic functions of SnTe in alloys. The thus-obtained data combined with the SnTe thermodynamic functions were used to calculate the partial molar functions of tin in alloys. The thus-obtained values and the equilibrium solid phase diagram of the SnTe–Sb2Te3–Te system, together with the relevant thermodynamic functions of Sb2Te3, were used to calculate the standard Gibbs free energies of formation and enthalpies of formation and the standard entropies of formation for SnSb2Te4, SnSb4Te7, and Sb2Te3- and SnTe-base solid solutions.
Similar content being viewed by others
REFERENCES
A. V. Shevelkov, Russ. Chem. Rev. 77, 1 (2008). https://doi.org/10.1070/RC2008v077n01ABEH003746
L. E. Shelimova, O. G. Karpinskii, P. P. Konstantinov, et al., Inorg. Mater. 40, 451 (2004). https://doi.org/10.1023/B:INMA.0000027590.43038.a8
J. Zhang, Y. Yan, H. Xie, et al., Ceram. Int. 45, 16039 (2019). https://doi.org/10.1016/j.ceramint.2019.05.119
P. Hu, TR. Wei, P. Qiu, et al., ACS Appl. 11, 34046 (2019). https://doi.org/10.1021/acsami.9b12854
C. Lee, J. N. Kim and J.-Y. Tak, et al., AIP Adv. 8, P. 115213 (2018). https://doi.org/10.1063/1.5047823
L. Pan, J. Li, D. Berardan, et al., J. Solid State Chem. 225, 168 (2015). https://doi.org/10.1016/j.jssc.2014.12.016
W. Ma, M. C. Record, J. Tian, et al., Materials 14, 4086 (2021). https://doi.org/10.3390/ma14154086
P. Guo, A. M. Sarangan, and I. Agha, Appl. Sci. 9, 530 (2019). https://doi.org/10.3390/app9030530
M. Wuttig and S. Raoux, Z. Anorg. Allg. Chem. 638, 2455 (2012). https://doi.org/10.1002/zaac.201200448
J. Tominaga, MRS Bull. 43, 347 (2018). https://doi.org/10.1557/mrs.2018.94
A. Sterzi, G. Manzoni, A. Crepaldi, et al., J. Electron. Spectrosc. Relat. Phenom. 225, 23 (2018). https://doi.org/10.1016/j.elspec.2018.03.004
Z. Wu, G. Liang, W. K. Pang, et al., Adv. Mater. 32, 1905632 (2020). https://doi.org/10.1002/adma.201905632
P. Mal, G. Bera, G. R. Turpu, et al., Phys. Chem. Chem. Phys. 21, 15030 (2019). https://doi.org/10.1002/adma.20190563210.1039/c9-cp01494b
Y. Hattori, Y. Tokumoto, K. Kimoto, et al., Sci. Rep. 10, 7957 (2020). https://doi.org/10.1002/adma.20190563210.1038/s41-598-020-64742-6
E. P. Amaladass, S. Sharma, A. T. Satya, et al., AIP Conf. Proc. 1951, 020015 (2018). https://doi.org/10.1063/1.5031723
M. Nurmamat, K. Okamoto, S. Zhu, et al., ACS Nano 14, 9059 (2020). https://doi.org/10.1021/acsnano.0c04145
I. A. Shvets, I. I. Klimovskikh, Z. S. Aliev, et al., Phys. Rev. 96, 235124 (2017). https://doi.org/10.1103/PhysRevB.96.235124
D. Pacile, S. V. Eremeev, M. Caputo, et al., Phys. Status Solidi RRL 12, 1800341 (2018). https://doi.org/10.1002/pssr.201800341
R. Vilaplana, J. A. Sans, F. J. Manjon, et al., J. Alloys Compd. 685, 962 (2016). https://doi.org/10.1016/j.jallcom.2016.06.170
M. B. Babanly, E. V. Chulkov, Z. S. Aliev, et al., Russ. J. Inorg. Chem. 62, 1703 (2017). https://doi.org/10.1134/S0036023617130034
M. B. Babanly, L. F. Mashadiyeva, D. M. Babanly, et al., Russ. J. Inorg. Chem. 13, 1649 (2019). https://doi.org/10.1134/S0036023619130035
A. G. Morachevskii, G. F. Voronin, V. A. Geiderikh, and I. B. Kutsenok, Electrochemical Research Methods in the Thermodynamics of Metallic Systems (ITsK Akademkniga, Moscow, 2003) [in Russian].
M. B. Babanly and Yu. A. Yusibov, Electrochemical Methods in Thermodynamics of Inorganic Systems (ELM, Baku, 2011) [in Russian].
V. P. Vassiliev and V. A. Lysenko, Electrochim. Acta 222, 1770 (2016). https://doi.org/10.1016/j.electacta.2016.11.075
V. Vassiliev and W. Gong, Electrochemical Cells—New Advances in Fundamental Researches and Applications, Ed. by Yan Shao (IntechOpen, 2012). https://doi.org/10.5772/39007
G. S. Hasanova, A. I. Aghazade, S. Z. Imamaliyeva, et al., JOM 73, 1511 (2021). https://doi.org/10.1007/s11837-021-04621-1
S. Z. Imamaliyeva, S. S. Musayeva, D. M. Babanly, et al., Thermochim. Acta 679, 178319 (2019). https://doi.org/10.1016/j.tca.2019.178319
E. G. Osadchii, Ya. I. Korepanov, and N. N. Zhdanov, Instrum. Exper. Techniques 59, 302 (2016). https://doi.org/10.1134/S0020441216010255
E. N. Ismailova, L. F. Mashadieva, D. M. Babanly, et al., Russ. J. Inorg. Chem. 61, 96 (2021). https://doi.org/10.1134/S0036023621010046
I. J. Alverdiev, V. A. Abbasova, Y. A. Yusibov, et al., Russ. J. Electrochem. 54, 195 (2018). https://doi.org/10.1134/S1023193518020027
M. Moroz, F. Tesfaye, P. Demchenko, et al., Thermochim. Acta 698, 178862 (2021). https://doi.org/10.1016/j.tca.2021.178862
M. Moroz, F. Tesfaye, P. Demchenko, et al., Energies 14, 1314 (2021). https://doi.org/10.3390/en14051314
L. E. Shelimova, V. N. Tomashik, and V. I. Grytsiv, State Diagrams in Semiconductor Materials Science. Handbook (Nauka, Moscow, 1991) [in Russian].
E. I. Elagina and N. K. Abrikosov, Russ. J. Inorg. Chem. 4, 1638 (1959).
T. Hirai, Y. Takeda, and K. Kurata, J. Less-Common Met. 13, 352 (1967). https://doi.org/10.1016/0022-5088(67)90143-9
A. Stegherr, Philips Res. Rep. 24, 72 (1969).
F. N. Guseinov, A. E. Seidzade, Y. A. Yusibov, and M. B. Babanly, Inorg Mater. 53, 354 (2017). https://doi.org/10.1134/S0020168517040057
A. E. Seidzade, E. N. Orujlu, T. Doert, et al., J. Phase Equilib. Diffus. 42, 373 (2021). https://doi.org/10.1007/s11669-021-00888-8
N. K. Abrikosov, V. F. Bankina, L. V. Poretskaya, et al., Semiconducting II–VI, IV–VI, and V–VI Compounds (Springer US, 1969).
N. K. Abrikosov and V. F. Bankina, Russ. J. Inorg. Chem. 3, 659 (1958).
L. E. Shelimova, O. G. Karpinsky, V. I. Kosyakov, et al., J. Struct. Chem. 41, 81 (2000). https://doi.org/10.1007/BF02684732
G. S. Hasanova, A. I. Aghazade, D. M. Babanly, et al., J. Therm. Anal. Calorim. (2021). https://doi.org/10.1007/s10973-021-10975-0
T. M. Alakbarova, H. J. Meyer, E. N. Orujlu, et al., Phase Transit. 94, 366 (2021). https://doi.org/10.1080/01411594.2021.1937625
T. B. Massalski, Binary Alloys Phase Diagrams (ASM International, Materials park, Ohio, 1990).
Database of Thermal Constants of Substances, Ed. by V. S. Yungman (2006). http://www.chem.msu.su/cgi-bin/tkv.
O. Kubaschewski, C. B. Alcock, and P. J. Spenser, Materials Thermochemistry, Sixth Ed. (Pergamon Press, 1993).
Ya. I. Gerasimov, A. N. Krestovnikov, and S. I Gorbov, Chemical Thermodynamics in Non-Ferrous Metallurgy. Directory (Metallurgiya, Moscow, 1974) [in Russian].
B. T. Melekh, S. A. Semenkovich, and A. A. Andreev, Thermodynamic Properties of Intermetallic Phases (Izd-vo IPM, Kiev, 1982) [in Russian].
Ya. I. Gerasimov and A. V. Nikol’skaya, Proceedings on the Fourth Symposium on Problems in the Metallurgy and Physics of Semiconductor Materials, 1961, p. 30.
S. A. Semenkovich and B. T. Melekh, Chemical Bonds in Solids, Ed. by N. N. Sirota (Consultants Bureau, New York, 1972). https://doi.org/10.1007/978-1-4684-1686-2_27
I. H. McAteer and H. Seltz, J. Am. Chem. Soc. 58, 2081 (1936).
Funding
The work was fulfilled in the frame of the scientific program of the “Candidate Spintronics Materials and Quantum Computations” international laboratory instituted by the Institute of Catalysis and Inorganic Chemistry of the National Academy of Sciences of Azerbaijan (Azerbaijan) and the Donostia International Physical Center (Spain), and was in part supported by the Science Development Foundation under the President of the Azerbaijan Republic (project No. EIF-GAT-5-2020-3(37)-12/02/4-M-02).
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
The authors declare that they have no conflicts of interest.
Additional information
Translated by O. Fedorova
Supplementary Information
Rights and permissions
About this article
Cite this article
Seidzade, A.E., Orujlu, E.N., Babanly, D.M. et al. Solid-Phase Equilibria in the SnTe–Sb2Te3–Te System and the Thermodynamic Properties of the Tin–Antimony Tellurides. Russ. J. Inorg. Chem. 67, 683–690 (2022). https://doi.org/10.1134/S003602362205014X
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S003602362205014X