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Synthesis, Crystal Structure, and Thermal Expansion of Sodium Barium Zirconium Phosphate–Sulfate

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Abstract

The phosphate–sulfate synthesis approach preventing the elimination of sulfur in the process of synthesis has been tested for NaBa6Zr(PO4)5SO4 as an example. The phase formation and thermal stability of phosphate–sulfate have been studied by X-ray diffraction and DTA-TG. The NaBa6Zr(PO4)5SO4 structure (space group I\(\overline 4 \)3d, a = 10.5449(3) Å, V = 1172.54(5) Å3, Z = 4) allied to the eulytite mineral has been refined by the Rietveld method. The structure is formed by wavy chains of edge-sharing (Na,Ba,Zr)O6-octahedra and (P,S)O4-tetrahedra sharing apices with the octahedra. Using thermal X-ray diffraction, it has been established that phosphate–sulfate is a strongly expanding material (αа = αb = αc = 13.3 × 10–6°C–1).

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ACKNOWLEDGMENTS

The equipment of the Shared Facilities Center “new Materials and Resource-Saving Technologies” of the Lobachevskii National Research State University was used in this work.

Funding

This work was financially supported by the Russian Foundation for Basic Research (project no. 18-29-12063) with the use of the equipment of the Shared Facilities Center “New Materials and Resource-Saving Technologies” of the Lobachevskii National Research State University.

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Authors and Affiliations

  1. Lobachevskii National Research State University, 603950, Nizhny Novgorod, Russia

    V. I. Pet’kov, A. I. Bokov, E. A. Asabina & M. I. Lelet

  2. National University of Science and Technology “Moscow Institute of Steel and Alloys”, 119049, Moscow, Russia

    A. M. Koval’skii

Authors
  1. V. I. Pet’kov
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  2. A. I. Bokov
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  3. E. A. Asabina
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  4. M. I. Lelet
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  5. A. M. Koval’skii
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Corresponding author

Correspondence to V. I. Pet’kov.

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Translated by E. Glushachenkova

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Pet’kov, V.I., Bokov, A.I., Asabina, E.A. et al. Synthesis, Crystal Structure, and Thermal Expansion of Sodium Barium Zirconium Phosphate–Sulfate. Russ. J. Inorg. Chem. 64, 1354–1358 (2019). https://doi.org/10.1134/S0036023619110159

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  • DOI: https://doi.org/10.1134/S0036023619110159

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