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Synthesis, phase formation, and thermal expansion of sulfate phosphates with the NaZr2(PO4)3 structure

  • Physical Methods of Investigation
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Abstract

The NaFeZr(PO4)2SO4 and Pb2/3FeZr(PO4)7/3(SO4)2/3 sulfate phosphates with the NaZr2(PO4)3 (NZP) structure were synthesized and studied using X-ray diffraction, electron microprobe analysis, IR spectroscopy, and simultaneous differential thermal and thermogravimetric analysis. The phase formation and thermal stability of the compounds were studied by powder X-ray diffraction and DTA–TG. The Pb2/3FeZr(PO4)7/3(SO4)2/3 structure was refined by full-profile analysis. The structure framework is composed of randomly occupied (Fe,Zr)O6 octahedra and (P,S)O4 tetrahedra; the Pb2+ ions occupy extra-framework sites. The thermal expansion of Pb2/3FeZr(PO4)7/3(SO4)2/3 in the temperature range from–120 to 200°C was studied by temperature X-ray diffraction. In terms of the average linear coefficient of thermal expansion (αav = 1.7 × 10–6°C–1), this compound can be classified as having low expansion. The combination of different tetrahedral anions (a phosphorus and a smaller sulfur one) in the NZP resulted in a decrease in the framework size and cavities and enabled the preparation of low-expansion sulfate phosphate with a smaller extra-framework cation (cheap Pb) instead of larger cations (Cs, Ba, Sr) used most often in the monoanionic phosphates.

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References

  1. M. E. Brownfield, E. E. Foord, S. J. Sutley, et al., Am. Mineral. 78, 653 (1993).

    CAS  Google Scholar 

  2. V. I. Pet’kov, Russ. Chem. Rev. 81, 606 (2012).

    Article  Google Scholar 

  3. M. V. Sukhanov, V. I. Pet’kov, V. S. Kurazhkovskaya, et al., Russ. J. Inorg. Chem. 51, 706 (2006).

    Article  Google Scholar 

  4. M. V. Sukhanov, V. I. Pet’kov, D. V. Firsov, et al., Russ. J. Inorg. Chem. 56, 1351 (2011).

    Article  CAS  Google Scholar 

  5. V. I. Pet’kov, M. V. Sukhanov, A. S. Shipilov, et al., Russ. J. Inorg. Chem. 58, 1015 (2013).

    Article  Google Scholar 

  6. V. I. Pet’kov, M. V. Sukhanov, A. S. Shipilov, et al., Inorg. Mater. 50, 263 (2014).

    Article  Google Scholar 

  7. V. I. Pet’kov, A. S. Shipilov, M. V. Sukhanov, et al., Russ. J. Inorg. Chem. 59, 1201 (2014).

    Article  Google Scholar 

  8. A. K. Ivanov-Shits and I. V. Murin, Solid-State Ionics (Izd. SPbGU, St. Petersburg, 2001), Vol. 1 [in Russian].

    Google Scholar 

  9. V. I. Pet’kov and A. I. Orlova, Inorg. Mater. 39, 1013 (2003).

    Article  Google Scholar 

  10. N. Anantharamulu, Rao K. Koteswara, G. Rambabu, et al., J. Mater. Sci. 46, 2821 (2011).

    Article  CAS  Google Scholar 

  11. V. I. Pet’kov, A. I. Orlova, G. N. Kasantsev, et al., J. Therm. Anal. Cal. 66, 623 (2001).

    Article  Google Scholar 

  12. S. Y. Limaye, D. K. Agrawal, and H. A. McKinstry, J. Am. Ceram. Soc. 70, 232 (1987).

    Article  Google Scholar 

  13. H. Miyazaki, I. Ushiroda, D. Itomura, et al., Jpn. J. Appl. Phys. 47, 7262 (2008).

    Article  CAS  Google Scholar 

  14. B. Zhang and J. Guo, J. Eur. Ceram. Soc. 15, 929 (1995).

    Article  CAS  Google Scholar 

  15. P. Oikonomou, Ch. Dedeloudis, C. J. Stournaras, et al., J. Eur. Ceram. Soc. 27, 1253 (2007).

    Article  CAS  Google Scholar 

  16. V. I. Pet’kov and E. A. Asabina, Glass Ceram., 61, 233 (2004).

    Article  Google Scholar 

  17. J. Alamo and R. Roy, J. Solid State Chem. 51, 270 (1984).

    Article  CAS  Google Scholar 

  18. R. Masse, J. C. Guitel, and R. Perret, Bul. Soc. Fr. Mineral. Crist. 96, 346 (1973).

    CAS  Google Scholar 

  19. P. R. Slater and C. Greaves, J. Mater. Chem. 2, 1267 (1992).

    Article  CAS  Google Scholar 

  20. P. R. Slater and C. Greaves, J. Mater. Chem. 4, 1469 (1994).

    Article  CAS  Google Scholar 

  21. M. V. Sukhanov, V. I. Pet’kov, and D. V. Firsov, Inorg. Mater. 47, 674 (2011).

    Article  CAS  Google Scholar 

  22. H. M. Rietveld, Acta Crystallogr. 22, 151 (1967).

    Article  CAS  Google Scholar 

  23. Y. I. Kim and F. Izumi, J. Ceram. Soc. Jpn. 102, 401 (1994).

    Article  CAS  Google Scholar 

  24. F. Izumi, The Rietveld Method, Ed. by R. A. Ch. Young (Oxford Univ. Press, New York, 1993).

  25. G. Buvanesvari and U. V. Varadaraju, J. Solid State Chem. 145, 227 (1999).

    Article  Google Scholar 

  26. H. Y-P. Hong, Mater. Res. Bul. 11, 173 (1976).

    Article  CAS  Google Scholar 

Download references

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Authors and Affiliations

  1. Lobachevsky State University of Nizhny Novgorod, pr. Gagarina 23, Nizhny Novgorod, 603950, Russia

    V. I. Pet’kov, A. S. Dmitrienko & M. V. Sukhanov

  2. National University of Science and Technology MISiS, Moscow, Russia

    A. M. Koval’skii

  3. Moscow State University, Vorob’evy gory, Moscow, 119991, Russia

    E. Yu. Borovikova

Authors
  1. V. I. Pet’kov
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  2. A. S. Dmitrienko
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  3. M. V. Sukhanov
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  4. A. M. Koval’skii
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  5. E. Yu. Borovikova
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Correspondence to V. I. Pet’kov.

Additional information

Original Russian Text © V.I. Pet’kov, A.S. Dmitrienko, M.V. Sukhanov, A.M. Koval’skii, E.Yu. Borovikova, 2016, published in Zhurnal Neorganicheskoi Khimii, 2016, Vol. 61, No. 5, pp. 654–660.

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Pet’kov, V.I., Dmitrienko, A.S., Sukhanov, M.V. et al. Synthesis, phase formation, and thermal expansion of sulfate phosphates with the NaZr2(PO4)3 structure. Russ. J. Inorg. Chem. 61, 623–629 (2016). https://doi.org/10.1134/S0036023616050168

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  • DOI: https://doi.org/10.1134/S0036023616050168

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