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Synthesis and Structure of Heterobinuclear Complexes [AuCl(μ-Dien*)PtCl3] and [AuCl(μ-Dien*)PtCl3] · 0.5H2O

  • Coordination Compounds
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Abstract

New binuclear complexes [AuCl(μ-Dien*)PtCl3] and [AuCl(μ-Dien*)PtCl3] · 0.5H2O, where Dien* is deprotonated diethylenetriamine, have been prepared and studied by elemental analysis, X-ray diffraction, and IR spectroscopy. The crystal structures are built of binuclear complexes of the composition [AuCl(μ-Dien*)PtCl3] with the average Au⋯Pt intramolecular distance equal to 3.403 Å. Gold and platinum atoms have distorted square coordination; the (AuN3Cl) and (PtNCl3) coordination cores are found; the middle Dien nitrogen atom acts as a bridge bonding the Au and Pt coordination squares.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Russian Academy of Sciences, Siberian Branch, Novosibirsk, 630090, Russia

    E. V. Makotchenko, I. A. Baidina & I. V. Korol’kov

  2. Novosibirsk State University, Novosibirsk, 630090, Russia

    E. V. Makotchenko & I. V. Korol’kov

Authors
  1. E. V. Makotchenko
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  2. I. A. Baidina
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  3. I. V. Korol’kov
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Correspondence to E. V. Makotchenko.

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Makotchenko, E.V., Baidina, I.A. & Korol’kov, I.V. Synthesis and Structure of Heterobinuclear Complexes [AuCl(μ-Dien*)PtCl3] and [AuCl(μ-Dien*)PtCl3] · 0.5H2O. Russ. J. Inorg. Chem. 64, 41–48 (2019). https://doi.org/10.1134/S0036023619010157

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