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New Heteronuclear Supramolecular Assemblies Based on a Robson-Type Macrocycle: Structure and Spectroscopic Properties

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Abstract

Novel tetraiminodiphenolate (tidf2−) supramolecular assemblies containing palladium, cobalt, copper and iron(II) have been prepared and characterized by X-ray crystallography, and FTIR and UV–Vis spectroscopies. Complex 1 crystallizes as [PdCo(tidf)(H2O)2]2([Fe(CN)5NO])2·7H2O, and contains a planar macrocycle, while complex 2, [PdCu(tidf)(H2O)(ClO4)]2([Fe(CN)4(CNH)2])·2H2O, shows a slightly bent heterocyclic unit. Both structures exhibited supramolecular architectures maintained through extensive hydrogen bonding networks.

Graphical Abstract

Two unique polynuclear complexes 2[PdCo(tidf)(H2O)2]([Fe(CN)5)NO])2·7H2O and 2[PdCu(tidf)(H2O)(ClO4)]([Fe(CN)4(CNH)2])·2H2O (tidf is a symmetrical tetraiminodiphenolate Robson type macrocyclic ligand) were prepared and their molecular structures and spectroscopic properties are discussed.

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Acknowledgements

DLH and FSN thank CAPES and CNPq for research funds and fellowships. Also, we thank Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES, PVE A099/2013 and PNPD 2376/2011).

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Authors and Affiliations

  1. Departamento de Química, Universidade Federal do Paraná, Cx. Postal 19081, Curitiba, PR, 81531-980, Brazil

    Marcelo Carpes Nunes, André Luis Rüdiger & Fábio Souza Nunes

  2. School of Chemistry, University of East Anglia, Norwich, NR4 7TJ, UK

    David L. Hughes

Authors
  1. Marcelo Carpes Nunes
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  2. André Luis Rüdiger
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  3. David L. Hughes
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  4. Fábio Souza Nunes
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Correspondence to Fábio Souza Nunes.

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Nunes, M.C., Rüdiger, A.L., Hughes, D.L. et al. New Heteronuclear Supramolecular Assemblies Based on a Robson-Type Macrocycle: Structure and Spectroscopic Properties. J Chem Crystallogr 48, 200–208 (2018). https://doi.org/10.1007/s10870-018-0728-0

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  • DOI: https://doi.org/10.1007/s10870-018-0728-0

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