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Synthesis and Spectral Properties of Ni(II), Pd(II), Pt(II), and Pt(IV) Tetraphenyltetrabenzoporphyrinates

  • Physical Chemistry of Solutions
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Abstract

Complexation reactions of 5,10,15,20-tetraphenyltetrabenzoporphyrin and transmetallation of its cadmium complex with nickel(II) acetate, Ni(II), Pd(II), and Pt(II) chlorides in dimethylformamide and phenol have been studied. The corresponding Ni(II), Pd(II), and Pt(II) porphyrinates have been synthesized. PtIVBr2 porphyrinate has been obtained by the treatment of Pt(II) 5,10,15,20-tetraphenyltetrabenzoporphyrinate with bromine in chloroform. The obtained compounds have been characterized by elemental analysis, electronic absorption and 1H NMR spectroscopy and mass spectrometry.

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Authors and Affiliations

  1. Krestov Institute of Solution Chemistry, Russian Academy of Sciences, Ivanovo, 153045, Russia

    N. V. Chizhova, O. V. Mal’tseva, R. S. Kumeev & N. Zh. Mamardashvili

Authors
  1. N. V. Chizhova
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  2. O. V. Mal’tseva
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  3. R. S. Kumeev
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  4. N. Zh. Mamardashvili
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Corresponding author

Correspondence to N. V. Chizhova.

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Original Russian Text © N.V. Chizhova, O.V. Mal’tseva, R.S. Kumeev, N.Zh. Mamardashvili, 2018, published in Zhurnal Neorganicheskoi Khimii, 2018, Vol. 63, No. 5, pp. 650–654.

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Chizhova, N.V., Mal’tseva, O.V., Kumeev, R.S. et al. Synthesis and Spectral Properties of Ni(II), Pd(II), Pt(II), and Pt(IV) Tetraphenyltetrabenzoporphyrinates. Russ. J. Inorg. Chem. 63, 682–686 (2018). https://doi.org/10.1134/S0036023618050200

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  • DOI: https://doi.org/10.1134/S0036023618050200

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