Skip to main content
SpringerLink
Log in

Comparative Structural Characteristic of Aqueous Lanthanide Chloride Solutions at 1 : 40 Molar Ratio from X-ray Diffraction Data

  • Physical Methods of Investigation
  • Published:
Russian Journal of Inorganic Chemistry Aims and scope Submit manuscript

Abstract

Aqueous lanthanide chloride solutions with 1 : 40 molar ratio have been studied by X-ray diffraction. Quantitative characteristics of the short-range environment of ions in solutions have been determined using model approach to analysis of experimental data. It has been confirmed that the number of molecules in the short-range environment decreases from nine to eight on passing from light to heavy cations. In so doing, three-caped trigonal prism coordination spheres of cations become two-caped one. Cations also form second coordination spheres composed of 8–10 solvent molecules. Noncontact ion associates form in all the systems.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. I. Persson, P. D’Angelo, S. De Panfilis, et al., Chemistry 14, 3056 (2008).

    Article  CAS  PubMed  Google Scholar 

  2. M. Duvail, R. Spezia, and P. Vitorge, ChemPhysChem 9, 693 (2008).

    Article  CAS  PubMed  Google Scholar 

  3. J. Zhang, N. Heinz, and M. Dolg, Inorg. Chem. 53, 7700 (2014).

    Article  CAS  PubMed  Google Scholar 

  4. F. Sessa, R. Spezia, and P. D’Angelo, J. Chem. Phys. 144, 204505 (2016).

    Article  CAS  PubMed  Google Scholar 

  5. P. R. Smirnov and V. N. Trostin, Russ. J. Gen. Chem. 82, 360 (2012).

    Article  CAS  Google Scholar 

  6. P. R. Smirnov and O. V. Grechin, Russ. J. Phys. Chem. A 91, 654 (2017).

    Article  CAS  Google Scholar 

  7. O. V. Grechin and P. R. Smirnov, Russ. J. Gen. Chem. 84, 617 (2014).

    Article  CAS  Google Scholar 

  8. G. Johansson and M. Sandsrom, Chem. Scr. 4 (5) 195 (1973).

    CAS  Google Scholar 

  9. A. K. Lyashchenko, Zh. Fiz. Khim. 66, 167 (1992).

    CAS  Google Scholar 

  10. T. Kowall, F. Foglia, L. Helm, et al., J. Am. Chem. Soc. 117, 3790 (1995).

    Article  CAS  Google Scholar 

  11. T. Yaita, H. Narita, Sh. Suzuki, et al., J. Radioanal. Nucl. Chem. 239, 371 (1999).

    Article  CAS  Google Scholar 

  12. T. Kimura and Y. Kato, J. Alloys Compd. 278, 92 (1998).

    Article  CAS  Google Scholar 

  13. V. Sharma, F. Böhm, M. Seitz, et al., Phys. Chem. Chem. Phys. 15, 8383 (2013).

    Article  CAS  PubMed  Google Scholar 

  14. H. Grigoriew and S. Siekierski, J. Phys. Chem. 97, 5400 (1993).

    Article  CAS  Google Scholar 

  15. A. Habenschuss and F. H. Spedding, J. Chem. Phys. 70, 3758 (1979).

    Article  CAS  Google Scholar 

  16. A. Habenschuss and F. H. Spedding, J. Chem. Phys. 70, 2797 (1979).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Krestov Institute of Solution Chemistry, Russian Academy of Sciences, Ivanovo, 153045, Russia

    P. R. Smirnov

  2. Research Institute of Thermodynamics and Kinetics of Chemical Processes, Ivanovo State University of Chemistry and Technology, Ivanovo, 153000, Russia

    O. V. Grechin

Authors
  1. P. R. Smirnov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. O. V. Grechin
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to P. R. Smirnov.

Additional information

Original Russian Text © P.R. Smirnov, O.V. Grechin, 2018, published in Zhurnal Neorganicheskoi Khimii, 2018, Vol. 63, No. 5, pp. 635–639.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Smirnov, P.R., Grechin, O.V. Comparative Structural Characteristic of Aqueous Lanthanide Chloride Solutions at 1 : 40 Molar Ratio from X-ray Diffraction Data. Russ. J. Inorg. Chem. 63, 665–669 (2018). https://doi.org/10.1134/S0036023618050170

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036023618050170

Search

Navigation