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Hexa(isothiocyanato)chromates(III) of Some Yttrium Group Lanthanide(III) and Europium Complexes with Nicotinic Acid: Synthesis and Crystal Structures

  • Coordination Compounds
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Abstract

Double ionic complexes [M(C5H5NCOO)3(H2O)2][Cr(NCS)6] · nH2O, where M = Eu (I), n = 1.15; Dy (II), Er (III), n = 1.5; M = Yb (IV), n = 2, have been synthesized by the reaction between M(NO3)3, M = Eu, Dy, Er, Yb, K3[Cr(NCS)6], and nicotinic acid (C5H5NCOO) in an aqueous solution and studied by chemical analysis, IR spectroscopy, and X-ray diffraction. Crystals of complexes I–IV are monoclinic, space group P21/n, Z = 4; a = 9.5358(2) Å, b = 25.4871(5) Å, c = 15.4303(4) Å, β = 105.513(1)°, V = 3613.6(1) Å3, ρcalcd = 1.799 g/cm3 for I, a = 9.5901(5) Å, b = 25.8599(15) Å, c = 15.6316(9) Å, β = 106.829(2)°, V = 3710.6(4) Å3, ρcalcd = 1.782 g/cm3 for II, a = 9.5640(3) Å, b = 25.8936(11) Å, c = 15.6498(7) Å, β = 106.895(2)°, V = 3708.3(3) Å3, ρcalcd = 1.791 g/cm3 for III, and a = 9.5049(2) Å, b = 25.6378(4) Å, c = 15.5120(3) Å, β = 106.934(1)°, V = 3616.1(1) Å3, ρcalcd = 1.864 g/cm3 for IV.

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Authors and Affiliations

  1. T.F. Gorbachev Kuzbass State Technical University, Kemerovo, 650000, Russia

    E. V. Cherkasova & T. G. Cherkasova

  2. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russia

    N. V. Pervukhina & N. V. Kuratieva

  3. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russia

    I. Yu. Bagryanskaya

  4. Novosibirsk National Research State University, Novosibirsk, 630090, Russia

    N. V. Kuratieva & I. Yu. Bagryanskaya

Authors
  1. E. V. Cherkasova
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  2. N. V. Pervukhina
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  3. N. V. Kuratieva
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  4. I. Yu. Bagryanskaya
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  5. T. G. Cherkasova
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Correspondence to E. V. Cherkasova.

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Original Russian Text © E.V. Cherkasova, N.V. Pervukhina, N.V. Kuratieva, I.Yu. Bagryanskaya, T.G. Cherkasova, 2018, published in Zhurnal Neorganicheskoi Khimii, 2018, Vol. 63, No. 5, pp. 596–600.

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Cherkasova, E.V., Pervukhina, N.V., Kuratieva, N.V. et al. Hexa(isothiocyanato)chromates(III) of Some Yttrium Group Lanthanide(III) and Europium Complexes with Nicotinic Acid: Synthesis and Crystal Structures. Russ. J. Inorg. Chem. 63, 626–630 (2018). https://doi.org/10.1134/S003602361805011X

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  • DOI: https://doi.org/10.1134/S003602361805011X

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