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Solubility in the diagonal sections of the 2KCl + Ca(NO3)2 ⇆ 2KNO3 + CaCl2–H2O system

  • Physicochemical Analysis of Inorganic Systems
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Abstract

Solubility data in the diagonal sections of the quaternary reciprocal 2KCl + Ca(NO3)2 → 2KNO3 + CaCl2–H2O system at 25 and 15°C are presented. It has been shown that the quaternary system has no stable diagonal at the studied temperatures, but contains a stable pair of salts, namely, potassium nitrate and calcium chloride. The obtained data can be used to optimize the thermal and concentrational parameters of the synthesis of potassium nitrate from calcium nitrate and potassium chloride.

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References

  1. S. N. Shoikhet, USSR Inventor’s Certificate No. 31004 (1933).

  2. F. Frowein and E. Rahles, US Patent No. 1835704 (1931).

  3. W. Hasselder, US Patent No. 2751280 (1956).

  4. M. K. Rustambekov, A. L. Taran, V. P. Danilov, et al., RF Patent No. 2206506 (2003).

  5. R. Flatt, A. Flatt, and J.-P. Flatt, US Patent No. 3361522 (1964).

  6. Yu. A. Ivanov, B. A. Dmitrevskii, L. I. Musienko, et al., USSR Inventor’s Certificate No. 1495298 (1989).

  7. O. B. Abramov, E. V. Afanasenko, A. S. Dedov, et al., RF Patent No. 2261227 (2005).

  8. G. Pipko, WO Patent No. 01/77019 (2001).

  9. T. W. Segar and SinGo. Ting, US Patent No. 3433584 (1969).

  10. Shangwen Tang, People’s Rep. Chin. Patent No. 1706748 (2005).

    Google Scholar 

  11. J. Kritschewsky and E. Goldman, Z. Anorg. Allg. Chem. 215, 103 (1933).

    Article  Google Scholar 

  12. V. P. Danilov, V. T. Orlova, S. K. Myasnikova, et al., Khim. Tekhnol. 7, 4 (2006).

    Google Scholar 

  13. G. Mocioaca, O. Popa, I. Doca, et al., Rev. Chim. 46, 994 (1995).

    CAS  Google Scholar 

  14. V. B. Kogan, V. G. Fridman, and V. V. Kafarov, The Solubility Handbook (Nauka, Leningrad, 1970), Vol. 3, Book 3 [in Russian].

    Google Scholar 

  15. N. I. Nikurashina and R. V. Mertslin, The Sections Method. Application to Study Multiphase States of Multinary Systems (Saratovsk. Univ., Saratov, 1969) [in Russian].

    Google Scholar 

  16. E. F. Zhuravlev and A. D. Sheveleva, Zh. Neorg. Khim. 5, 2630 (1960).

    CAS  Google Scholar 

  17. M. N. Viktorov, Graphic Estimations in Industrial Chemistry of Inorganic Compounds (Khimiya, Leningrad, 1972) [in Russian].

    Google Scholar 

  18. S. A. Mazunin, S. I. Frolova, and N. S. Kistanova, RF Patent No. 2416790 (2011).

  19. Yu. Yu. Lur’e, The Analytical Chemistry of Sewages (Khimiya, Moscow, 1984) [in Russian].

    Google Scholar 

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Correspondence to O. S. Kudryashova.

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Original Russian Text © O.S. Kudryashova, N.S. Kistanova, 2016, published in Zhurnal Neorganicheskoi Khimii, 2016, Vol. 61, No. 12, pp. 1658–1662.

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Kudryashova, O.S., Kistanova, N.S. Solubility in the diagonal sections of the 2KCl + Ca(NO3)2 ⇆ 2KNO3 + CaCl2–H2O system. Russ. J. Inorg. Chem. 61, 1596–1600 (2016). https://doi.org/10.1134/S0036023616120093

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  • DOI: https://doi.org/10.1134/S0036023616120093

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