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Hydrothermal synthesis of nanodispersed α-Fe2O3 with a lamellar shape of crystals

  • Synthesis and Properies of Inorganic Compounds
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Abstract

Transformations of oxyhydroxides of iron(III), which are formed in the process of oxidation of iron(II) in Fe(OH)2 suspensions upon the hydrothermal treatment at 150–220°C in water and in aqueous solutions of potassium hydroxide with concentrations of 1–5 mol/L have been studied. The dependences of the phase composition and dispersity of the arising products and the morphology of α-Fe2O3 on the parameters of heat treatment and on the phase composition of FeOOH have been determined. Conditions for obtaining nanodisperse α-Fe2O3 with a lamellar shape of crystals have been refined.

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Authors and Affiliations

  1. South Ural State University (National Research University), pr. Lenina 76, Chelyabinsk, 454080, Russia

    V. Sh. Mirasov, D. A. Zherebtsov, D. G. Kleshchev & I. V. Krivtsov

  2. Institute of Chemistry, Komi Research Center, Ural Branch, Russian Academy of Sciences, ul. Pervomaiskaya 48, Syktyvkar, 167982, Russia

    Yu. I. Ryabkov

  3. OOO Research Institute of Pigment Materials, Kaslinskaya ul. 3, Chelyabinsk, 454084, Russia

    V. A. German

Authors
  1. V. Sh. Mirasov
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  2. D. A. Zherebtsov
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  3. D. G. Kleshchev
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  4. Yu. I. Ryabkov
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  5. V. A. German
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  6. I. V. Krivtsov
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Correspondence to V. Sh. Mirasov.

Additional information

Original Russian Text © V.Sh. Mirasov, D.A. Zherebtsov, D.G. Kleshchev, Yu.I. Ryabkov, V.A. German, I.V. Krivtsov, 2014, published in Zhurnal Neorganicheskoi Khimii, 2014, Vol. 59, No. 6, pp. 703–711.

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Mirasov, V.S., Zherebtsov, D.A., Kleshchev, D.G. et al. Hydrothermal synthesis of nanodispersed α-Fe2O3 with a lamellar shape of crystals. Russ. J. Inorg. Chem. 59, 529–535 (2014). https://doi.org/10.1134/S003602361406014X

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  • DOI: https://doi.org/10.1134/S003602361406014X

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