Abstract
The composition and ionic character of formation of binary extractants based on quaternary ammonium bases and organic acids were confirmed using spectral and quantum-chemical methods, the structures of the binary extractants were obtained. The energy of bond between cation and anion in molecules of the binary extractants was determined, it is by an order of magnitude higher than the energy of H bond and close to the energy of chemical (ionic) bond.
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Original Russian Text © Yu.A. Zakhodyaeva, V.V. Belova, A.A. Voshkin, 2014, published in Zhurnal Neorganicheskoi Khimii, 2014, Vol. 59, No. 1, pp. 85–94.
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Zakhodyaeva, Y.A., Belova, V.V. & Voshkin, A.A. IR spectral and quantum-chemical studies of binary extractants. Russ. J. Inorg. Chem. 58, 1584–1592 (2013). https://doi.org/10.1134/S0036023614010203
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DOI: https://doi.org/10.1134/S0036023614010203