Skip to main content
SpringerLink
Log in

Formation of diamonds and other carbon phases upon the destruction of palladium carbonyl clusters

  • Synthesis and Properties of Inorganic Compounds
  • Published:
Russian Journal of Inorganic Chemistry Aims and scope Submit manuscript

Abstract

Carbonyl clusters of general composition Pd x (CO) y Cl z , which are formed when solutions of chloropalladium(II)complexes are exposed to carbon monoxide, are shown to experience spontaneous destruction to yield palladium powder, CO2, CO, and carbon phases, in particular a diamond phase, due to the occurrence of the Boudoir reaction. The diamond is in the form of grains with sizes of ≤1 mm and diamond filaments with diameters of up to ten micrometers and lengths of up to 2 cm.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. J. H. Darling and J. S. Ogden, J. Chem. Soc. (D), No. 10, 1079 (1973).

    Google Scholar 

  2. E. Harbeck and G. Lunge, Z. Anorg. Allg. Chem. 16(1), 50 (1898).

    CAS  Google Scholar 

  3. Organometallic Chemistry, Ed. by H. Zeiss (Reinhold, New York, 1960; Mir, Moscow, 1964).

    Google Scholar 

  4. O. A. Belyakova, Ya. V. Zubavichus, and Yu. L. Slovokhotov, Proceedings of the 4th All-Russia Conference on Cluster Chemistry (Ivanovo, 2004), p. 78 [in Russian].

    Google Scholar 

  5. V. I. Spitsyn, I. V. Fedoseev, and I. V. Znamenskii, Zh. Neorg. Khim. 25, 2754 (1980).

    CAS  Google Scholar 

  6. I. V. Fedoseev, L. V. Shevnitsyna, and A. S. Gordeev, Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol. 48(12), 16 (2005).

    CAS  Google Scholar 

  7. I. V. Fedoseev and A. S. Gordeev, Zh. Neorg. Khim. 52, 12 (2007).

    CAS  Google Scholar 

  8. R. Torecki and R. R. Schock, J. Am. Chem. Soc. 112, 2448 (1990).

    Article  Google Scholar 

  9. B. C. Gates, Chem. Rev. 95, 511 (1995).

    Article  CAS  Google Scholar 

  10. Z. C. Zhang and W. M. K. Sachtler, J. Mol. Catal. 67, 349 (1991).

    Article  CAS  Google Scholar 

  11. A. P. Rudenko, I. I. Kulakova, and V. A. Skvortsova, Usp. Khim. 62(2), 95 (1993).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Kaluga Branch, Bauman Moscow State Technical University, ul. Bazhenova 4, Kaluga, 248004, Russia

    I. V. Fedoseev, A. P. Korzhavyi & K. V. Maramygin

Authors
  1. I. V. Fedoseev
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. P. Korzhavyi
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. K. V. Maramygin
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Original Russian Text © I.V. Fedoseev, A.P. Korzhavyi, K.V. Maramygin, 2013, published in Zhurnal Neorganicheskoi Khimii, 2013, Vol. 58, No. 12, pp. 1586–1588.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Fedoseev, I.V., Korzhavyi, A.P. & Maramygin, K.V. Formation of diamonds and other carbon phases upon the destruction of palladium carbonyl clusters. Russ. J. Inorg. Chem. 58, 1443–1445 (2013). https://doi.org/10.1134/S0036023613120097

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036023613120097

Keywords

Search

Navigation