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Structure of reaction products of hydrous and anhydrous zinc acetates with 1,10-phenanthroline

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Abstract

A reaction of aqueous zinc acetate with 1,10-phenanthroline produces the ionic complex [(Phen)2Zn(OOCMe)](OOCMe) · 5H2O. A similar reaction of “anhydrous zinc acetate” [Zn7(μ4-O)2(μ-OOCMe)10][η-OC(Me)OHNEt3]2 in benzene yields a precipitate, which is recrystallized from acetonitrile into trinuclear (Phen)2Zn3(μ-OOCMe)6; and the reaction in acetonitrile yields mononuclear (Phen)Zn(OOCMe)2 · MeCN. These complexes have been characterized by single-crystal X-ray diffraction.

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Authors and Affiliations

  1. Kurhakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    M. A. Uvarova, E. V. Kushan & S. E. Nefedov

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  1. M. A. Uvarova
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  2. E. V. Kushan
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  3. S. E. Nefedov
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Correspondence to S. E. Nefedov.

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Original Russian Text © M.A. Uvarova, E.V. Kushan, S.E. Nefedov, 2012, published in Zhurnal Neorganicheskoi Khimii, 2012, Vol. 57, No. 4, pp. 577–586.

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Uvarova, M.A., Kushan, E.V. & Nefedov, S.E. Structure of reaction products of hydrous and anhydrous zinc acetates with 1,10-phenanthroline. Russ. J. Inorg. Chem. 57, 515–524 (2012). https://doi.org/10.1134/S0036023612040249

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  • DOI: https://doi.org/10.1134/S0036023612040249

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