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Conversions of zinc cimantrenates in reactions with 1,10-phenanthroline

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Abstract

The reaction between aqueous zinc acetate and cimantrene carboxylic acid has been found to yield Zn[(OOCC5H4)Mn(CO)3] 2[O(H)Me]4, whose dissolution in tetrahydrofuran (THF) gives trinuclear Zn3[μ-(OOCC5H4)Mn(CO)3]4[μ-η2-(OOCC5H4)Mn(CO)3]2(THF)4. Labile THF molecules can be replaced by bidentate 1,10-phenanthroline under mild conditions, thus resulting in Phen2Zn3[μ-(OOCC5H4)Mn(CO)3]4[μ-η2- (OOCC5H4)Mn(CO)3]2. Variations in the reagent ratio and the reaction conditions result in mononuclear PhenZn[(OOCC5H4)Mn(CO)3]2(H2O), which contains a coordinated water molecule. The synthesized complexes have been separated with high yields in the form of single crystals and characterized by chemical analysis, IR spectroscopy, and X-ray diffraction.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    M. A. Uvarova, A. A. Ageshina & S. E. Nefedov

Authors
  1. M. A. Uvarova
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  2. A. A. Ageshina
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  3. S. E. Nefedov
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Correspondence to M. A. Uvarova.

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Original Russian Text © M.A. Uvarova, A.A. Ageshina, S.E. Nefedov, 2015, published in Zhurnal Neorganicheskoi Khimii, 2015, Vol. 60, No. 10, pp. 1326–1333.

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Uvarova, M.A., Ageshina, A.A. & Nefedov, S.E. Conversions of zinc cimantrenates in reactions with 1,10-phenanthroline. Russ. J. Inorg. Chem. 60, 1210–1217 (2015). https://doi.org/10.1134/S0036023615100198

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  • DOI: https://doi.org/10.1134/S0036023615100198

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