Abstract
Processes that occur in strong alkaline solutions of iridium(III) and iridium(IV) hydroxo complexes have been studied by EPR and electronic absorption spectroscopy. It has been demonstrated that dissolution of iridium compounds in alkaline solutions should be accompanied by a series of complicated transformations involving oxygen, which lead to the formation of several binuclear iridium(III, III), (III, IV), and (IV, IV) dioxygen complexes.
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Original Russian Text © D.A. Pankratov, P.N. Komozin, Yu.M. Kiselev, 2011, published in Zhurnal Neorganicheskoi Khimii, 2011, Vol. 56, No. 11, pp. 1877–1882.
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Pankratov, D.A., Komozin, P.N. & Kiselev, Y.M. EPR spectroscopy of transformations of iridium(III) and iridium(IV) hydroxo complexes in alkaline media. Russ. J. Inorg. Chem. 56, 1794–1799 (2011). https://doi.org/10.1134/S0036023611110210
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DOI: https://doi.org/10.1134/S0036023611110210