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Determination of hydration numbers by IR spectrometry

  • Physical Chemistry of Solutions
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Abstract

The use of precision IR spectrometry for determining the hydration numbers of species in organic phase was considered. The hydration numbers of HAuCl4 (n = 3), HFeCl4 (n = 3), HNO3 (n = 0), HClO4 (n = 2), and HCl (n = 1) in 0.64 M (15 vol. %) TBP in CCl4 were determined.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. akademika Lavrent’eva 3, Novosibirsk, 630090, Russia

    V. V. Troshin, I. V. Mironov & L. A. Sheludyakova

Authors
  1. V. V. Troshin
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  2. I. V. Mironov
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  3. L. A. Sheludyakova
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Additional information

Original Russian Text © V.V. Troshin, I.V. Mironov, L.A. Sheludyakova, 2009, published in Zhurnal Neorganicheskoi Khimii, 2009, Vol. 54, No. 12, pp. 2100–2103.

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Troshin, V.V., Mironov, I.V. & Sheludyakova, L.A. Determination of hydration numbers by IR spectrometry. Russ. J. Inorg. Chem. 54, 2018–2021 (2009). https://doi.org/10.1134/S0036023609120304

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  • DOI: https://doi.org/10.1134/S0036023609120304

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