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Polynuclear thallium(I) N,N-cyclo-hexamethylenedithiocarbamate [Tl2{S2CN(CH2)6}2] n : Chemisorption properties and copper(II) fixation modes

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Abstract

The Cu2+ sorption properties of the polynuclear thallium(I) N,N-cyclo-hexamethylenedithiocarbamate complex [Tl2{S2CN(CH2)6}2]n (I) are reported. The sorption capacity of the complex is ∼67 mg/g. According to EPR data, freshly precipitated I binds copper from the aqueous phase by chemisorption, which results in the formation of the β-form of the paramagnetic trinuclear complex [CuTl2{S2CN(CH2)6}4] (containing a small amount of its α-form). Scanning electron microscopic data indicate cardinal reformation of the chemisorbent particles upon copper(II) sorption, including changes in the particle shape and size.

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References

  1. G. I. Tsizin and Yu. A. Zolotov, Zh. Anal. Khim. 57(7), 678 (2002) [J. Anal. Chem. 57 (7), 562 (2002)].

    Google Scholar 

  2. R. Hering, Chelatbildende Ionenaustauscher (Academie, Berlin, 1967; Mir, Moscow, 1971).

    Google Scholar 

  3. G. V. Myasoedova and S. B. Savvin, Chelating Sorbents(Nauka, Moscow, 1984) [in Russian].

    Google Scholar 

  4. K. M. Saldadze and V. D. Kopylova-Valova, Complexing Ion Exchengers (Complexites) (Khimiya, Moscow, 1980) [in Russian].

    Google Scholar 

  5. S. B. Savvin, V. P. Dedkova, and O. P. Shvoeva, Usp. Khim. 69(3), 203 (2000).

    Google Scholar 

  6. O. B. Mokhodoeva, G. V. Myasoedova, and I. V. Kubrakova, Zh. Anal. Khim. 62(7), 679 (2007) [J. Anal. Chem. 62 (7), 607 (2007)].

    Google Scholar 

  7. V. M. Ivanov, R. A. Polyanskov, and A. A. Sedova, Vestn. Mosk. Univ., Ser. 2: Khim. 46(1), 61 (2005).

    CAS  Google Scholar 

  8. A. V. Ivanov, O. V. Loseva, and A. V. Gerasimenko, Koord. Khim. 34(6), 421 (2008).

    Google Scholar 

  9. A. V. Ivanov, O. A. Bredyuk, A. V. Gerasimenko, et al., Koord. Khim. 32(5), 354 (2006).

    Google Scholar 

  10. T. A. Rodina, O. A. Bredyuk, A. V. Ivanov, et al., Zh. Neorg. Khim. 54(8), 1310 (2009).

    CAS  Google Scholar 

  11. I. V. Ovchinnikov and V. N. Konstantinov, J. Magn. Reson. 32, 179 (1978).

    CAS  Google Scholar 

  12. Ph. H. Rieger, Electron Spin Resonance (Senior Reporter Symons M.C.R.) Athenaeum, Newcastle upon Tyne, 1993), Vol. 13B, 178.

    Google Scholar 

  13. A. V. Ivanov and P. M. Solozhenkin, Zh. Neorg. Khim. 35(6), 1537 (1990).

    CAS  Google Scholar 

  14. A. V. Ivanov and P. M. Solozhenkin, Khamkar Mukhammad Zafar, et al., Koord. Khim. 15(9), 1223 (1989).

    CAS  Google Scholar 

Download references

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Authors and Affiliations

  1. Amur State University, Ignatíevskoe sh. 21, Blagoveshchensk, 675027, Russia

    T. A. Rodina

  2. Institute of Geology and Nature Management, Far Eastern Branch, Russian Academy of Sciences, Relochnyi per. 1, Blagoveshchensk, 675000, Russia

    A. V. Ivanov, O. V. Loseva & O. A. Bredyuk

Authors
  1. T. A. Rodina
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  2. A. V. Ivanov
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  3. O. V. Loseva
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  4. O. A. Bredyuk
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Correspondence to A. V. Ivanov.

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Original Russian Text © T.A. Rodina, A.V. Ivanov, O.V. Loseva, O.A. Bredyuk, 2009, published in Zhurnal Neorganicheskoi Khimii, 2009, Vol. 54, No. 12, pp. 2046–2050.

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Rodina, T.A., Ivanov, A.V., Loseva, O.V. et al. Polynuclear thallium(I) N,N-cyclo-hexamethylenedithiocarbamate [Tl2{S2CN(CH2)6}2] n : Chemisorption properties and copper(II) fixation modes. Russ. J. Inorg. Chem. 54, 1964–1968 (2009). https://doi.org/10.1134/S0036023609120201

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  • DOI: https://doi.org/10.1134/S0036023609120201

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