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Nitration of rhodium(III) sulfates

  • Physical Methods of Investigation
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Abstract

Nitration of sulfate complexes of rhodium has been investigated by NMR 103Rh, 14N, 15N, and 17O NMR. At high pH, [Rh(NO2)6]3−, dimer [Rh2(μ-OH)2(NO2)8]4−, and trimer [Rh3(μ-OH)4(OH)(NO2)9]5− are the dominant species in solutions.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090, Russia

    S. N. Shagabutdinova & A. V. Belyaev

  2. Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent’eva 5, Novosibirsk, 630090, Russia

    M. A. Fedotov

Authors
  1. S. N. Shagabutdinova
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  2. M. A. Fedotov
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  3. A. V. Belyaev
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Correspondence to A. V. Belyaev.

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Original Russian Text © S.N. Shagabutdinova, M.A. Fedotov, A.V. Belyaev, 2009, published in Zhurnal Neorganicheskoi Khimii, 2009, Vol. 54, No. 8, pp. 1359–1364.

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Shagabutdinova, S.N., Fedotov, M.A. & Belyaev, A.V. Nitration of rhodium(III) sulfates. Russ. J. Inorg. Chem. 54, 1290–1295 (2009). https://doi.org/10.1134/S003602360908018X

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  • DOI: https://doi.org/10.1134/S003602360908018X

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