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Photoactivation of Rhodium(III) Complexes

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Abstract

Photolysis of [Rh(NH3)5NO2](NO3)2 aqueous solutions is studied using 15N NMR spectroscopy. It is established that irradiation at room temperature leads to the exchange of nitrite ligand 15NO −2 by 14NO −2 in the complex with a measurable rate. In dark conditions, the process is not observed for several weeks. A mechanism of photolysis is proposed.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    A. V. Belyaev, S. V. Tkachev & S. N. Vorob’eva

Authors
  1. A. V. Belyaev
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  2. S. V. Tkachev
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  3. S. N. Vorob’eva
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Correspondence to S. N. Vorob’eva.

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The authors declare that they have no conflict of interests.

Russian Text © The Author(s), 2020, published in Zhurnal Strukturnoi Khimii, 2020, Vol. 61, No. 2, pp. 252–261.

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Belyaev, A.V., Tkachev, S.V. & Vorob’eva, S.N. Photoactivation of Rhodium(III) Complexes. J Struct Chem 61, 238–246 (2020). https://doi.org/10.1134/S0022476620020080

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  • DOI: https://doi.org/10.1134/S0022476620020080

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