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Synthesis, crystal structure and properties of [Nd(C6NO2H5)3(H2O)2]2n · (nH5O2)(nHgCl5)(2nHgCl4) · (nH2O) with unprecedented polycationic chains

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Abstract

A novel inorganic-organic hybrid complex, [Nd [Nd (C6NO2H5)3(H2O)2]2n · (nH5O2)(nHgCl5)(2nHgCl4) · (nH2O)(1), was obtained by hydrothermal reactions and structurally characterized by X-ray diffraction. The unit cell parameters are as follows: a = 9.579(1), b = 21.462(2), c = 15.801(1) Å, β = 102.339(6)ℴ, V = 3173.5(5) Å3, Z = 4, space group P21/c. The crystal structure analysis reveals that the title complex is characteristic of a novel polycationic [Nd(C6NO2H5)3(H2O)2] 6n+2n one-dimensional chain-like structure. Photoluminescent investigation shows that the title complex displays strong emission in blue region, which is attributed to the intraligand π-π*-transition of nicotinic ligands. Optical absorption spectra of 1 reveal the presence of an optical gap of 3.45 eV.

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  1. College of Chemistry and Chemical Engineering, Jiangxi Province Key Laboratory of Coordination Chemistry, Jinggangshan University, 343009, Ji’an, Jiangxi, P.R. China

    W. -T. Chen

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Chen, W.T. Synthesis, crystal structure and properties of [Nd(C6NO2H5)3(H2O)2]2n · (nH5O2)(nHgCl5)(2nHgCl4) · (nH2O) with unprecedented polycationic chains. Russ. J. Inorg. Chem. 54, 1230–1235 (2009). https://doi.org/10.1134/S0036023609080105

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  • DOI: https://doi.org/10.1134/S0036023609080105

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