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Potassium peroxostannate nanoparticles

  • Synthesis and Properties of Inorganic Compounds
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Abstract

Stable amorphous potassium peroxostannate nanoparticles with controlled sizes (10–100 nm), morphology, and hydrogen peroxide percentage (19–30 wt %) were synthesized for the first time. The compounds were characterized by vibrational spectroscopy, 119Sn MAS NMR spectroscopy, powder X-ray diffraction, and thermogravimetry. These characteristics were compared to those for K2Sn(OH)6 and K2Sn(OOH)6. Potassium peroxostannate particles are mainly built of peroxo-bridged polymer chains. The particles are stable when stored in a dry state or suspended in nonaqueous solvents; in contact with water, they release hydrogen peroxide.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    E. A. Legurova, T. A. Tripol’skaya & P. V. Prikhodchenko

  2. Institute of Chemistry, Hebrew University of Jerusalem, Jerusalem, Israel

    S. Sladkevich & O. Lev

  3. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent’eva 5, Novosibirsk, 630090, Russia

    M. A. Fedotov & D. F. Khabibulin

Authors
  1. E. A. Legurova
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  2. S. Sladkevich
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  3. O. Lev
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  4. M. A. Fedotov
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  5. D. F. Khabibulin
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  6. T. A. Tripol’skaya
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  7. P. V. Prikhodchenko
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Additional information

Original Russian Text © E.A. Legurova, S. Sladkevich, O. Lev, M.A. Fedotov, D.F. Khabibullin, T.A. Tripol’skaya, P.V. Prikhodchenko, 2009, published in Zhurnal Neorganicheskoi Khimii, 2009, Vol. 54, No. 6, pp. 889–893.

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Legurova, E.A., Sladkevich, S., Lev, O. et al. Potassium peroxostannate nanoparticles. Russ. J. Inorg. Chem. 54, 824–828 (2009). https://doi.org/10.1134/S0036023609060023

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  • DOI: https://doi.org/10.1134/S0036023609060023

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