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Tetraphenylantimony perrhenate and tetraphenylantimony chlorate: Syntheses and structures

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Abstract

The reaction of tetraphenylantimony chloride with sodium perrhenate or potassium chlorate yields tetraphenylantimony perrhenate (I) and tetraphenylantimony chlorate (II), respectively. Complex I was also synthesized from pentaphenylantimony and triphenylantimony diperrhenate in toluene. According to X-ray diffraction, crystals I and II consist of almost regular tetrahedral tetraphenylstibonium cations (CSbC, 109.4(2)°–109.5(7)° in I and 109.1(1)°–109.6(1)° in II) and [ReO4]− (OreO, 107.6(3)°–113.3(5)°) and [ClO3]− (OClO, 96.3(9)°, 116.4(5)°) anions, respectively. The average Sb-C bond lengths (2.094(3) Å in I, 2.097(2) Å in II) are close to the sum of the covalent radii of the Sb and C atoms. The average distances Re-O in complex I (1.672(4) Å) and Cl-O in complex II (1.315 Å) correspond to multiple bonds.

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Authors and Affiliations

  1. Blagoveshchensk State Pedagogical University, Blagoveshchensk, Russia

    V. V. Sharutin, V. S. Senchurin & O. K. Sharutina

  2. Far East State Agrarian University, Blagoveshchensk, Russia

    O. A. Fastovets & A. P. Pakusina

Authors
  1. V. V. Sharutin
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  2. V. S. Senchurin
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  3. O. A. Fastovets
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  4. A. P. Pakusina
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  5. O. K. Sharutina
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Original Russian Text © V.V. Sharutin, V.S. Senchurin, O.A. Fastovets, A.P. Pakusina, O.K. Sharutina, 2009, published in Zhurnal Neorganicheskoi Khimii, 2009, Vol. 54, No. 3, pp. 436–442.

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Sharutin, V.V., Senchurin, V.S., Fastovets, O.A. et al. Tetraphenylantimony perrhenate and tetraphenylantimony chlorate: Syntheses and structures. Russ. J. Inorg. Chem. 54, 389–395 (2009). https://doi.org/10.1134/S0036023609030103

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  • DOI: https://doi.org/10.1134/S0036023609030103

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