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Crystal structures of La1 − x Sr2 + x (GeO4)(V1 − x Mo x O4) (x= 0−0.4) solid solutions

  • Physicochemical Analysis of Inorganic Systems
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Abstract

The phase compositions of theLaVO4-SrMoO4(1) and Sr2GeO4-SrMoO4 (2) binary systems, which bound the Sr2GeO4-LaVO4-SrMoO4 (3) ternary system, and the LaSr2(VO4)(GeO4)-Sr2GeO4+SrMoO4 section (4) of system 3 are studied at subsolidus temperatures. Systems 1 and 2 consist of a mixture of the initial compounds, and the La1 − x Sr2 + x (GeO4)(V1 − x Mo x O4) (where 0 ≤ x ≤ 0.4) region of substitutional solid solutions with a palmierite structure is formed in system 3. The unit cell parameters of the solid solutions are determined. The distribution of the lanthanum and strontium cations over two positions of the cationic sublattice is described.

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Authors and Affiliations

  1. Institute of Solid-State Chemistry, Ural Division, Russian Academy of Sciences, ul. Pervomaiskaya 91, Yekaterinburg, 620219, Russia

    V. D. Zhuravlev, V. G. Zubkov, A. P. Tyutyunnik & N. D. Koryakin

  2. Moscow State University, Moscow, 119991, Russia

    Yu. A. Velikodnyi

Authors
  1. V. D. Zhuravlev
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  2. V. G. Zubkov
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  3. A. P. Tyutyunnik
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  4. Yu. A. Velikodnyi
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  5. N. D. Koryakin
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Original Russian Text © V.D. Zhuravlev, V.G. Zubkov, A.P. Tyutyunnik, Yu.A. Velikodnyi, N.D. Koryakin, 2009, published in Zhurnal Neorganicheskoi Khimii, 2009, Vol. 54, No. 1, pp. 135–137.

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Zhuravlev, V.D., Zubkov, V.G., Tyutyunnik, A.P. et al. Crystal structures of La1 − x Sr2 + x (GeO4)(V1 − x Mo x O4) (x= 0−0.4) solid solutions. Russ. J. Inorg. Chem. 54, 134–136 (2009). https://doi.org/10.1134/S0036023609010227

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  • DOI: https://doi.org/10.1134/S0036023609010227

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