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Predicting the Stability of Orthoarsenates Lu1–xLnxAsO4, Ln = Sm–Yb, Sc, Y, and La1–xLnxAsO4, Ln = Ce, Pr, Nd Solid Solutions

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Nanomaterials and Nanocomposites, Nanostructure Surfaces, and Their Applications (NANO 2020)

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Abstract

Urusov’s crystal energy theory of isomorphous substitutions was used to calculate mixing energies (interaction parameters) and critical decomposition temperatures (stability temperatures) of solid solutions in the systems Lu1–xLnxAsO4, Ln = Sm–Yb, Sc, Y with zircon structure, and La1–xLnxAsO4, Ln = Ce, Pr, Nd with monazite structure. For the Lu1–xLnxAsO4 system, a diagram of the thermodynamic stability of solid solutions is built that makes it possible to predict the thermodynamic stability of solid solutions. It is characterized by the presence of regions of thermodynamic stability and metastability of solid solutions. Above the critical temperatures, solid solutions are thermodynamically stable, and below the critical temperatures, they are metastable. The present results can be useful in choosing the ratio of components in “mixed” matrices, the amount of activator in luminescent, laser, and other practically important materials, as well as in matrices for immobilization of toxic and radioactive waste.

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Acknowledgements

This study was carried out within the Fundamental Research Programme funded by the Ministry of Education and Science of Ukraine (grants ID 0119U100025 and 0120U102059).

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Authors and Affiliations

  1. Vasyl’ Stus Donetsk National University, Vinnytsia, 21027, Ukraine

    E. I. Get’man, Yu. A. Oleksii & S. V. Radio

  2. Vinnytsia National Technical University, Vinnytsia, 21000, Ukraine

    O. V. Kudryk

  3. Minnesota State University, Mankato, MN, 56001, USA

    L. I. Ardanova

Authors
  1. E. I. Get’man
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  2. Yu. A. Oleksii
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  3. O. V. Kudryk
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  4. S. V. Radio
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  5. L. I. Ardanova
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Corresponding author

Correspondence to S. V. Radio .

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Editors and Affiliations

  1. Institute of Physics, National Academy of Sciences of Ukraine, Kyiv, Ukraine

    Olena Fesenko

  2. Institute of Physics, National Academy of Sciences of Ukraine, Kyiv, Ukraine

    Leonid Yatsenko

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Get’man, E.I., Oleksii, Y.A., Kudryk, O.V., Radio, S.V., Ardanova, L.I. (2021). Predicting the Stability of Orthoarsenates Lu1–xLnxAsO4, Ln = Sm–Yb, Sc, Y, and La1–xLnxAsO4, Ln = Ce, Pr, Nd Solid Solutions. In: Fesenko, O., Yatsenko, L. (eds) Nanomaterials and Nanocomposites, Nanostructure Surfaces, and Their Applications . NANO 2020. Springer Proceedings in Physics, vol 263. Springer, Cham. https://doi.org/10.1007/978-3-030-74741-1_1

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