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Crystal structure of the reaction product of copper(II) nitrate with α-(3,3-Dimethyl-3,4-dihydro-1-isoquinolyl)hydroxy-iminoacetonitrile [Cu3(μ3-OH)(μ-L)3(NO3)2(H2O)] · 2H2O

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Abstract

The coordination compound [Cu3(μ3-OH)(μ-L)3(NO3)2(H2O)] · 2H2O (I), where L is the α-(3,3-dimethyl-3,4-dihydro-1-isoquinolyl)hydroxyiminoacetonitrile anion, has been synthesized. The crystal and molecular structure of I was determined by X-ray diffraction (Enraf-Nonius CAD4, MoK α radiation, graphite monochromator, ω-scan mode, 2θmax = 49.96°, 7673 unique reflections, a = 12.745(3) Å, b = 13.726(3) Å, c = 28.835(6) Å, β = 93.44(3)°, V = 5035.2(17) Å3, Z = 4, space group P21/c). In the trimer complex I, the copper atoms are combined by a bridging hydroxy group. The copper atoms are additionally linked pairswise by three tridentate chelating bridging organic anions coordinated to the Cu(II) atoms by the N and O atoms of the deprotonated oxime group and by the N atom of the dihydroisoquinoline moiety.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    V. I. Sokol & V. S. Sergienko

  2. Peoples Friendship University, ul. Miklukho-Maklaya 6, Moscow, 117198, Russia

    V. V. Davydov, N. Yu. Merkur’eva & E. I. Polyakova

  3. Institute of Technical Chemistry, Ural Division, Russian Academy of Sciences, ul. Lenina 13, Perm, 614600, Russia

    Yu. V. Shklyaev

Authors
  1. V. I. Sokol
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  2. V. V. Davydov
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  3. N. Yu. Merkur’eva
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  4. E. I. Polyakova
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  5. Yu. V. Shklyaev
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  6. V. S. Sergienko
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Original Russian Text © V.I. Sokol, V.V. Davydov, N. Yu. Merkur’eva, E.I. Polyakova, Yu.V. Shklyaev, V.S. Sergienko, 2007, published in Zhurnal Neorganicheskoi Khimii, 2007, Vol. 52, No. 10, pp. 1643–1652.

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Sokol, V.I., Davydov, V.V., Merkur’eva, N.Y. et al. Crystal structure of the reaction product of copper(II) nitrate with α-(3,3-Dimethyl-3,4-dihydro-1-isoquinolyl)hydroxy-iminoacetonitrile [Cu3(μ3-OH)(μ-L)3(NO3)2(H2O)] · 2H2O. Russ. J. Inorg. Chem. 52, 1541–1550 (2007). https://doi.org/10.1134/S0036023607100129

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  • DOI: https://doi.org/10.1134/S0036023607100129

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