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Reactions in the M(HCOO)2-CS(NH2)2-H2O (M = Mg, Mn, Cd) systems at 25°C

  • Physicochemical Analysis of Inorganic Systems
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Abstract

Complex formation in the M(HCOO)2-CS(NH2)2-H2O (M = Mg, Mn, Cd) systems at 25°C is studied using the isothermal solubility method. In the Cd(HCOO)2-CS(NH2)2-H2O system, a congruently dissolving compound Cd(HCOO)2 · 2CS(NH2)2 is found and characterized by X-ray powder diffraction and IR spectroscopy. The Mg(HCOO)2-CS(NH2)2-H2O and Mn(HCOO)2-CS(NH2)2-H2O systems are eutonics at this temperature. Data on carbamide and thiocarbamide complexes of divalent metal formates are systematized.

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Authors and Affiliations

  1. Institute of General and Inorganic Chemistry, Bulgarian Academy of Sciences, Sofia, Bulgaria

    V. Z. Vasileva

  2. South Western University “Neofit Rilski”, Blagoevgrad, Bulgaria

    P. P. Petrova

Authors
  1. V. Z. Vasileva
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  2. P. P. Petrova
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Original Russian Text © V.Z. Vasileva, P.P. Petrova, 2006, published in Zhumal Neorganicheskoi Khimii, 2006, Vol. 51, No. 5, pp. 880–884.

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Vasileva, V.Z., Petrova, P.P. Reactions in the M(HCOO)2-CS(NH2)2-H2O (M = Mg, Mn, Cd) systems at 25°C. Russ. J. Inorg. Chem. 51, 814–818 (2006). https://doi.org/10.1134/S0036023606050226

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  • DOI: https://doi.org/10.1134/S0036023606050226

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