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Transamination reaction of dimethylglyoxime on cobalt(III) matrix

  • Coordination Compounds
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Abstract

The [Co(DTOH)(DTO)] · 2H2O complex (I), where DTOH2 is diacetylmonooxime thiosemicarbazone (the transamination product of one oxime group of dimethylglyoxime with thiosemicarbazide), is synthesized by the reaction of a cobalt(II) salt, dimethylglyoxime, and thiosemicarbazide in the presence of Na3AlF6 in water solution in air.

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Original Russian Text © N.V. Gerbeleu, Yu.A. Simonov, O.A. Bologa, P.N. Bourosh, E.B. Koropchanu, 2006, published in Zhurnal Neorganicheskoi Khimii, 2006, Vol. 51, No. 5, pp. 785–787.

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Gerbeleu, N.V., Simonov, Y.A., Bologa, O.A. et al. Transamination reaction of dimethylglyoxime on cobalt(III) matrix. Russ. J. Inorg. Chem. 51, 717–719 (2006). https://doi.org/10.1134/S0036023606050056

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  • DOI: https://doi.org/10.1134/S0036023606050056

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