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Synthesis and Structure of Cobalt(III) Complex with Cyanomethylene and N,N′-Ethylenebis(3-methylsalicylideneiminate)

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Abstract

The new complex [CoIII(3-CH3Salen)(CH2CN)]·CH3CN was synthesized and its crystal structure was determined by the X-ray diffraction analysis. The cyanomethylene ligand is bound to the metallocenter by a Co‒C bond. In the crystalline state, an organometallic polymer structure is formed, in which metal atoms are interconnected by cyanomethylene bridges.

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Funding

This work was supported by the Council for Grants of the President of the Russian Federation (scholarship of the President of the Russian Federation no. SP-3405.2021.1, M.V. Novozhilova)

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Authors and Affiliations

  1. Ioffe Institute, Russian Academy of Sciences, 194021, St. Petersburg, Russia

    M. V. Novozhilova, M. P. Karushev & A. M. Timonov

  2. St. Petersburg State University, 199034, St. Petersburg, Russia

    D. V. Spiridonova

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  1. M. V. Novozhilova
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  2. D. V. Spiridonova
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  3. M. P. Karushev
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  4. A. M. Timonov
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Correspondence to A. M. Timonov.

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Novozhilova, M.V., Spiridonova, D.V., Karushev, M.P. et al. Synthesis and Structure of Cobalt(III) Complex with Cyanomethylene and N,N′-Ethylenebis(3-methylsalicylideneiminate). Russ J Gen Chem 92, 261–264 (2022). https://doi.org/10.1134/S1070363222020165

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  • DOI: https://doi.org/10.1134/S1070363222020165

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