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Metal exchange reactions between cadmium protoporphyrin and cobalt and zinc chlorides in acetonitrile and dimethyl sulfoxide

  • Physical Methods of Investigations
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Abstract

Metal exchange between cadmium protoporphyrin CdPP and zinc and cobalt chlorides in dimethyl sulfoxide (DMSO) and acetonitrile (AN) was studied by spectrophotometry. Comparative analysis of the data on metal exchange between CdPP and ZnCl2 in DMSO and between CdPP and CoCl2 in AN was performed. The possible exchange mechanisms were considered. The results were compared with the data on cadmium mesoporphyrin exchange with zinc and cobalt.

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References

  1. P. Hambright, The Porphyrin Handbook, Ed. by K. Smith, K. Kadish, and R. Guillard (Wiley, San Diego, 1990), Vol. 3, p. 129.

    Google Scholar 

  2. K. B. Yatsimirskii and Ya. D. Lampeka, Physical Chemistry of Metal Complexes with Macrocyclic Ligands (Naukova Dumka, Kiev, 1985), p. 217 [in Russian].

    Google Scholar 

  3. D. B. Berezin, O. V. Shukhto, and B. D. Berezin, Zh. Neorg. Khim. 47 (8), 1305 (2002) [Russ. J. Inorg. Chem. 47 (8), 1187 (2002)].

    CAS  Google Scholar 

  4. S. P. Gubin, Cluster Chemistry: Principles of Classification and Structure (Nauka, Moscow, 1987) [in Russian].

    Google Scholar 

  5. O. A. Reutov, I. P. Beletskaya, and V. I. Sokolov, Mechanisms of Reactions of Organometallic Compounds (Khimiya, Moscow, 1972) [in Russian].

    Google Scholar 

  6. F. Basolo and R. Pearson, Mechanisms of Inorganic Reactions: A Study of Metal Complexes in Solution (Wiley, New York, 1967; Mir, Moscow, 1971).

    Google Scholar 

  7. B. D. Berezin, S. V. Rumyantseva, and M. B. Berezin, Koord. Khim. 30 (4), 312 (2004).

    Google Scholar 

  8. M. B. Berezin, A. S. Semeikin, O. I. Koifman, and G. A. Krestov, Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol. 30 (1), 48 (1987).

    Google Scholar 

  9. B. D. Berezin, Coordination Compounds of Porphyrins and Phthalocyanine (Nauka, Moscow, 1978; Wiley, New York, 1981).

    Google Scholar 

  10. B. D. Berezin and O. A. Golubchikov, Coordination Chemistry of Solvates of Transition-Metal Salts (Nauka, Moscow, 1992) [in Russian].

    Google Scholar 

  11. K. B. Yatsimirskii, Thermochemistry of Complexes (Akad. Nauk SSSR, Moscow, 1951) [in Russian].

    Google Scholar 

  12. K. B. Yatsimirskii and V. P. Vasil’ev, Instability Constants of Complexes (Akad. Nauk SSSR, Moscow, 1959) [in Russian].

    Google Scholar 

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Zvezdina, S.V., Berezin, M.B. & Berezin, B.D. Metal exchange reactions between cadmium protoporphyrin and cobalt and zinc chlorides in acetonitrile and dimethyl sulfoxide. Russ. J. Inorg. Chem. 51, 112–117 (2006). https://doi.org/10.1134/S0036023606010189

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  • DOI: https://doi.org/10.1134/S0036023606010189

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