Abstract
The microstructure of the Al–0.3Sn–0.3Cu alloy and Al–0.3Sn–0.3Cu–0.15Zr alloy has been examined by X-ray diffraction (XRD), optical microscopy (OM), scanning electron microscopy (SEM), and transmission electron microscopy (TEM), the mechanical properties have been evaluated by the tensile strength and microhardness tests. After addition of Zr, fine Al3Zr precipitates provide a core for Sn during the solidification process; at the same time, Sn plays an important role in the distribution of θ(Al2Cu) phase. These reasons lead to demixing of the β(Sn) phase and Al2Cu phase obviously during the extrusion. Under the joint action of Al3Zr and Sn, the Sn–θ(Al2Cu) quasi-binary phase is distributed in the matrix uniformly. The Al3Zr particles hinder the dislocation slip, make the intermediate subboundaries keep a stable state, and enhance the recrystallization resistance. Based on these reasons, the mechanical properties of the Al–0.3Sn–0.3Cu–0.15Zr alloy have been significantly improved.
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REFERENCES
T. Desaki, Y. Goto, and S. Kamiya, “Development of the aluminum alloy bearing with higher wear resistance,” JSAE Rev. 21, 321–325 (2000).
J. Chashechkina, M. James, K. Lepper, and D. A. Rigney, “Sliding behavior of selected aluminum alloys,” Wear 46–56, 203–204 (1997).
B. C. Muddle and J. F. Nie, “Strengthening of an Al–Cu–Sn alloy by deformation-resistant precipitate plates,” Acta Mater. 56, 3490–3501 (2008).
X. Liu, Y. Ma, M. Q. Zeng, and M. Zhu, “Wear behavior of Al–Sn alloys with different distribution of Sn dispersoids manipulated by mechanical alloying and sintering,” Wear 265, 1857–1863 (2008).
J. Dai, C. Du, L. Yang, N. Zhang, and Y. Zhang, “Effect of aluminum concentration on the microstructure and mechanical properties of Sn–Cu–Al solder alloy,” Microelectron. Reliab. 55, 596–601 (2015).
H. M. Flower, S. Hirosawa, A. Kamio, and T. Sato, “Classification of the role of microalloying elements in phase decomposition of Al based alloys,” Acta Mater. 48, 1797–1806 (2000).
H. M. Flower and J. M. Silcock, “Comments on a comparison of early and recent work on the effect of trace additions of Cd, In, or Sn on nucleation and growth of θ′ in Al–Cu alloys,” Scr. Mater. 46, 389–394 (2002).
G. J. Auchterlonie, J. Drennan, S. H. Huo, and G. B. Schaffer, “The effect of trace elements on the sintering of an Al–Zn–Mg–Cu alloy,” Acta Mater. 49, 2671–2678 (2001).
N. A. Belov, A. O. Mikhailina, A. N. Alabin, and O. O. Stolyarova, “Calculation experimental study of the phase diagram AlCuSiSn in the domain of aluminum alloys " Metalloved. Term. Obrab. Met. No. 4, 11–17 (2016).
N. A. Belov, O. O. Stolyarova, and A. O. Yakovleva, “The effect of lead (Pb) on the structure and phase composition of the casting alloy Al–5% Si–4% Cu,” Russ. Metall. (Metally) 2016, 198–206 (2016). [in Russian].
N. A. Belov, O. O. Stolyarova, T. I. Murav’eva, and D. L. Zagorskii, “The phase composition and structure of aluminum alloys of the system Al–Cu–Si–Sn–Pb,” Phys. Met. Metallogr. 117, 579–587 (2016).
J. D. Robson, “A new model for prediction of dispersoid precipitation in aluminum alloys containing zirconium and scandium,” Acta Mater. 52, 1409–1421 (2004).
F. Jiang, Q. Pan, Z. Yin, and Y. Zhang, “Effect of minor Sc and Zr on the microstructure and mechanical properties of Al–Mg based alloys,” Mater. Sci. Eng., A 280, 151–155 (2000).
S. M. Bruemmer, L. M. Pawlowski, I. M. Robertson, and J. S. Vetrano, “Influence of the particle size on recrystallization and grain growth in Al–Mg–X alloys,” Mater. Sci. Eng., A 238, 101–107 (1997).
Y. Deng, Y. L. Duan, D. Xiao, G. F. Xu, Z. M. Yin, and L. Q. Zhou, “Excellent superplasticity and deformation mechanism of Al–Mg–Sc–Zr alloy processed via simple free forging,” Mater. Sci. Eng., A 624, 124–131 (2015).
N. Ryum, “Precipitation and recrystallization in an A1–0.5 wt % Zr alloy,” Acta Metall. 17, 269–278 (1969).
B. Baradarani and R. Raiszadeh, “Precipitation hardening of cast Zr-containing A356 aluminium alloy,” Mater. Des. 32, 935–940 (2011).
S. Rystad and R. Ryum, “A metallographical investigation of the precipitation and recrystallization process in an Al–Zr alloy,” Aluminium 53, 193–195 (1977).
E. Nesen, “Precipitation of the metastable cubic Al3Zr phase in subperitectic Al–Zr alloy,” Acta Metall. 20, 499–506 (1992).
Z-h. Jia, J-P. Couzinié, N. Cherdoudi, I. Guillot, L. Arnberg, P. Åsholt, S. Brusethaug, B. Barlas, and D. Massinon, “Precipitation behaviour of Al3Zr precipitate in Al–Cu–Zr and Al–Cu–Zr–Ti–V alloys,” Trans. Nonferrous Met. Soc. China 22, 1860–1865 (2012).
B. Li, C. Li, Q. Pan, and Z. Zhang, “Characterization of flow behavior and microstructural evolution of Al–Zn–Mg–Sc–Zr alloy using processing maps,” Mater. Sci. Eng., A 556, 844–848 (2012).
S. A. Alkahtani, H. W. Doty, A. M. Samuel, and F. H. Samuel, “Role of Zr and Sc addition in controlling the microstructure and tensile properties of aluminum–copper based alloys,” Mater. Des. 88, 1134–1144 (2015).
J. Gröbner, D. Mirković, and R. Schmid-Fetzer, “Liquid demixing and microstructure formation in ternary Al–Sn–Cu alloys,” Mater. Sci. Eng., A 487, 456–467 (2008).
P. D. Brown, S. J. Harris, A. Horlock, C. J. Kong, and D. G. McCartney, “TEM assessment of HVOLF thermally sprayed Al–12 wt % Sn–1 wt % Cu alloy,” Mater. Sci. Eng., A 375–377, 595–598 (2004).
P. D. Brown, S. J. Harris, C. J. Kong, and D. G. McCartney, “Analysis of microstructure formation in gas-atomised Al–12 wt. % Sn–1wt. % Cu alloy powder,” Mater. Sci. Eng., A 454–455, 252–259 (2007).
J. Drennan, D. Kent, and G. B. Schaffer, “Age hardening of a sintered Al–Cu–Mg–Si–(Sn) alloy,” Mater. Sci. Eng., A 405, 65–73 (2005).
A. N. Alabin, N. A. Belov, and I. A. Matveeva, “Optimization of phase composition of Al–Cu–Mn–Zr–Sc alloys for rolled products without requirement for solution treatment and quenching,” J. Alloys Compd. 583, 206–213 (2014).
M. M. Attar, B. Ramezanzadeh, and S. Sharifi Golru, “Effects of surface treatment of aluminum alloy 1050 on the adhesion and anticorrosion properties of the epoxy coating,” Appl. Surf. Sci. 345, 360–368 (2015).
Y-l. Deng, L. Wan, X-m. Zhang, and Y-y. Zhangm, “Effects of precipitation of Al3Zr particles on microstructures, textures and properties of Al–Zn–Mg–Cu alloy hot-rolled plate,” Chin. J. Nonferrous Met. 22, 358–364 (2012).
J-h. Chen, N-p. Jin, and H. Zhang, “Hot deformation behavior of Al–Zn–Mg–Cu–Zr aluminum alloys during compression at elevated temperature,” Trans. Nonferrous Met. Soc. China. 21, 437–442 (2011).
A. Azimi, A. Shokuhfar, and A. Zolriasatein, “Nanostructured Al–Zn–Mg–Cu–Zr alloy prepared by mechanical alloying followed by hot pressing,” Mater. Sci. Eng., A 595, 124–130 (2014).
X. G. Chen, J. Lai, and Z. Zhang, “The thermal stability of mechanical properties of Al–B4C composites alloyed with Sc and Zr at elevated temperatures,” Mater. Sci. Eng., A 532, 462–470 (2012).
B. Li, Q. Pan, and Z. Yin, “Characterization of hot deformation behavior of as-homogenized Al–Cu–Li–Sc–Zr alloy using processing maps,” Mater. Sci. Eng., A 614, 199–202 (2006).
L. Hu, D. L. Geng, B. Wei, and W. Zhai, “Thermodynamic properties and microstructure evolution of ternary Al–10%Cu–x%Sn immiscible alloys,” J. Alloys Compd. 627, 402–409 (2015).
Y. Baba and H. Yoshida, “The role of zirconium to improve strength and stress-corrosion resistance of Al–Zn–Mg and Al–Zn–Mg–Cu alloys,” Trans. Jpn. Inst. Met. 23, 620–630 (1982).
FUNDING
The project was supported by the State Key Development Program for Basic Research of China (grant no. 2012CB619504) and program for the 973 Program (nos. 2012CB619504 and 2014CB046702). We are grateful to Professor Y.C. Huang, Dr. Z.B. Xiao, Dr. Y. Liu, and Master Y. Li for their assistance.
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Xianwei Ren, Huang, Y. & Liu, Y. Effect of Zr Addition on Microstructure and Properties of Al–Sn–Cu Based Alloy. Phys. Metals Metallogr. 120, 694–701 (2019). https://doi.org/10.1134/S0031918X19070093
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DOI: https://doi.org/10.1134/S0031918X19070093