Skip to main content
Log in

Structural-phase composition, structure of the surface, magnetostatic and microwave properties of powders produced by milling of Fe in polystyrene with additions of surfactants

  • Electrical and Magnetic Properties
  • Published:
The Physics of Metals and Metallography Aims and scope Submit manuscript

Abstract

The effect of additions of surfactants (stearic and perfluorononanoic acids, stearylamine, and of their mixtures) on the morphology, structural-phase composition, structure of the surface, and magnetostatic and microwave properties of ferromagnetic powders obtained by the joint high-energy milling of Fe and polystyrene has been investigated. It has been shown that the use of a mixture of stearic and perfluorononanoic acids during milling made it possible to obtain particles of plate-like shape with minimum changes in the phase composition and to produce shells on their surface that consist of the surfactant molecules. All of these factors have positively affected the microwave properties of the composites prepared from thus obtained powders.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. J. R. Liu, M. Itoh, T. Horikawa, E. Taguchi, H. Mori, and K. Machida, “Iron based carbon nanocomposites for electromagnetic wave absorber with wide bandwidth in GHz range,” Appl. Phys. A 82, 509–513 (2006).

    Article  Google Scholar 

  2. Jia Huo, Li Wang, and Haojie Yu, “Polymeric nanocomposites for electromagnetic wave absorption,” J. Mater. Sci. 44, 3917–3927 (2009).

    Article  Google Scholar 

  3. E. P. Elsukov, K. N. Rozanov, S. F. Lomaeva, A. V. Osipov, D. A. Petrov, A. S. Shuravin, A. A. Chulkina, G. N. Konygin, and A. L. Ul’yanov, “Microwave Absorbing Properties of Fe Powders Milled in Various Media,” Phys. Met Metallogr. 106, 465–471 (2008).

    Article  Google Scholar 

  4. E. P. Elsukov, K. N. Rozanov, S. F. Lomaeva, A. V. Osipov, D. A. Petrov, D. V. Surnin, A. A. Chulkina, and A. S. Shuravin, “Structure, magnetostatic properties, and microwave characteristics of mechanoactivated nanocrystalline Fe and Fe-Si powders,” Phys. Met. Metallogr. 104, 248–256 (2007).

    Article  Google Scholar 

  5. A. N. Maratkanova, A. V. Syugaev, A. A. Shakov, O. Yu. Vilkov, and S. F. Lomayeva, “Thin organic layers grown on the surface of iron particles under high-energy ball milling in the presence of polystyrene and various surfactants: X-ray absorption and photoelectron spectroscopy studies,” J. Phys. Chem. C 116, 14005–14013 (2012).

    Article  Google Scholar 

  6. A. N. Maratkanova, A. V. Syugaev, and S. F. Lomaeva, “Formation of interfacial layer in Fe-polystyrene system during mechanochemical synthesis in the presence of alkyl surfactants,” Bull. Russ. Acad. Sci.: Physics 77, 221–225 (2013).

    Article  Google Scholar 

  7. S. F. Lomaeva, “Structural and phase transformations, thermal stability, and magnetic and corrosive properties of nanocrystalline iron-based alloys obtained by mechanoactivation in organic media,” Phys. Met. Metallogr. 104, 388–407 (2007).

    Article  Google Scholar 

  8. G. Le Cäer, J. M. Dubois, and J. P. Senateur, “Etude par spectrometrie Mössbayer des carbures de fer Fe3C et Fe5C2,” J. Solid State Chem. 19, 19–28 (1976).

    Article  Google Scholar 

  9. L. S. Vasil’ev and S. F. Lomayeva, “On the analysis of mechanism of supersaturation of metal powders with interstitial impurities during mechanoactivation,” J. Mater. Sci. 3, 5411–5415 (2004).

    Article  Google Scholar 

  10. S. F. Lomayeva, A. N. Maratkanova, O. M. Nemtsova, A. A. Chulkina, E. P. Yelsukov, “Formation of iron oxides during mechanoactivation in water and oxygencontaining organic liquids,” Nucl. Instr. Methods Phys. Res. A 575, 99–104 (2007).

    Article  Google Scholar 

  11. K. Nakanishi, Infrared Absorption Spectroscopy (Holden-Day, San Francisco, 1962; Mir, Moscow, 1965).

    Google Scholar 

  12. J. Kaal, A. M. Cortizas, O. Reyes, and M. Solino, “Molecular characterization of Ulex Europaeus biochar obtained from laboratory heat treatment experiments—A pyrolysis-GC/MS study,” J. Anal. Appl. Pyrol. 95, 205–212 (2012).

    Article  Google Scholar 

  13. D. W. Mayo, F. A. Miller, and R. W. Hannah, Course Notes on the Interpretation of Infrared and Raman Spectra (Wiley, New Jersey, 2003).

    Google Scholar 

  14. K. N. Rozanov, D. A. Petrov, A. N. Maratkanova, A. A. Chulkina, and C. F. Lomaeva, “Microwave properties of powders produced by high-energy milling of iron with paraffin,” Phys. Met. Metallogr. 115, 642–649 (2014).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to S. F. Lomaeva.

Additional information

Original Russian Text © S.F. Lomaeva, A.N. Maratkanova, A.V. Syugaev, K.N. Rozanov, D.A. Petrov, 2015, published in Fizika Metallov i Metallovedenie, 2015, Vol. 116, No. 8, pp. 803–810.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Lomaeva, S.F., Maratkanova, A.N., Syugaev, A.V. et al. Structural-phase composition, structure of the surface, magnetostatic and microwave properties of powders produced by milling of Fe in polystyrene with additions of surfactants. Phys. Metals Metallogr. 116, 760–767 (2015). https://doi.org/10.1134/S0031918X15080104

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0031918X15080104

Keywords

Navigation