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Physical nature of structural and phase transformations in Cu-Al α solid solutions upon low-temperature irradiation and subsequent annealing

  • Structure, Phase Transformations, and Diffusion
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Abstract

Methods of X-ray diffraction analysis and measurements of residual resistivity have been used to study effects of electron irradiation in the temperature range of 250–330 K on the structural and phase state of the Cu-15 at % Al solid solution. The results obtained are explained by the presence in the Cu-Al alloys of an inhomogeneous short-range order of two types, i.e., low-temperature, α2 type; and high-temperature, γ2 type.

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References

  1. E. M. Schulson, “The ordering and disordering of solid solutions under irradiation,” J. Nucl. Mater. 83, 239–264 (1979).

    Article  CAS  Google Scholar 

  2. H. J. Frost and K. C. Russell, “Precipitate stability under irradiation,” in Phase Transformations and Solute Redistribution in Alloys during Irradiation, Ed. by F. V. Nolfi (Applied Science Publ., London, 1983, pp. 75 113; Metallurgiya, Chelyabinsk, 1989, pp. 65–94).

    Google Scholar 

  3. A. Alamo, C. H. De Novion, and D. Lesueur, “Displacement threshold energy determination for Cu3Au and CuAu ordered alloys,” Radiat. Eff. Defects Solids 70(1–4), 157–172 (1989).

    Google Scholar 

  4. V. G. Vaks and S. V. Beiden, “Ordering phenomena in open systems: A model of an irradiated alloy in the self-consistent-field approximation,” J. Exper. Theor. Phys. 78, 546–557 (1994).

    Google Scholar 

  5. D. Rosenblatt, G. J. Dienes, and R. Smoluchovski, “Radiation induced changes in electrical resistivity of α-Brass,” J. Appl. Phys. 26, 1044–1049 (1955).

    Article  CAS  Google Scholar 

  6. W. Pfeiler and R. Poerschke, “Defect recovery and short-range order in some concentrated alloys after electron irradiation at 77 K,” J. Phys. F: Met. Phys. 17, 1043–1050 (1987).

    Article  CAS  Google Scholar 

  7. C. Kinoshita, K. Shinohara, and S. Kitajima, “Behaviors of point defects introduced into α-Cu-Al alloys by neutron irradiation at low temperature,” Ann. Rep. Res. Reactor Inst. Kyoto Univ., No. 9, 150–154 (1976).

    Google Scholar 

  8. M. S. Wechsler and R. H. Kernohan, “The effect of radiation of diffusion-controlled reaction in copperbased alloys,” in Radiation Damage in Solids (Int. Atomic Energy Agency, Vienna, 1962), vol. 2, pp. 81–109.

    Google Scholar 

  9. R. Poerschke and H. Wollenberger, “The decompositions of low temperature electron irradiated Cu-Ni alloys upon isochronal annealing,” Radiat. Eff. Defects Solids 49, 225–232 (1980).

    Article  CAS  Google Scholar 

  10. B. C. Zubchenko, P. V. Petrenko, and A. A. Tatarov, “Variation of resistivity upon low-temperature deformation and subsequent recovery of Ag-15 at % Al,” Dokl. Akad. Nauk Ukr. SSR, Ser. A., No. 6, 78–81 (1983).

    Google Scholar 

  11. B. C. Zubchenko, N. P. Kulish, and P. V. Petrenko, “Effect of low-temperature plastic deformation and subsequent annealing on the residual resistivity of Cu-Al alloys,” Metallofizika 2(3), 75–80 (1980).

    CAS  Google Scholar 

  12. C. Dimitrov and O. Dimitrov, “Composition dependence of defect properties in electron-irradiated Fe-Cr-Ni Solid Solutions,” J. Phys. F: Metall. Phys. 14, 793–811 (1984).

    Article  CAS  Google Scholar 

  13. Yu. M. Platov, L. M. Bystrov, and S. I. O. Sadykhov, “Variation of the resistivity of ordering alloys upon electron irradiation,” Izv. Akad. Nauk SSSR, Met., No. 2, 101–125 (1972).

    Google Scholar 

  14. P. V. Petrenko, N. A. Mel’nikova, Yu. E. Grabovskii, and N. P. Kulish, “Effect of short-range order on the vacancy swelling of solid solutions,” Vopr. At. Nauki Tech., Ser. Fiz. Radiats. Povrezhd. Radiats. Materialoved., No. 3, 27–33 (1999).

    Google Scholar 

  15. V. P. Kolotushkin, S. N. Votinov, and S. A. Nikulin, “Specific features of the structural state in radiationresistant structural materials,” Russ. Metall. (Metally), No. 3, 242–249 (2009).

    Google Scholar 

  16. N. P. Kulish and P. V. Petrenko, “Short-range order in binary solid solutions. Ordering and its change at heat in Fe-Al, Cu-Al and Ag-Al alloys,” Phys. Status Solidi A 120, 315–331 (1990).

    Article  CAS  Google Scholar 

  17. P. V. Petrenko, N. P. Kulish, N. A. Mel’nikova, and Yu. E. Grabovskii, “Effect of short-range order on the variation of residual resistivity in binary solid solutions,” Usp. Fiz. Met. 5, 401–432 (2004).

    CAS  Google Scholar 

  18. P. V. Petrenko, N. P. Kulish, N. A. Mel’nikova, and Yu. E. Grabovskii, “Short-range-order structure in nonsaturated Cu-Al α solid solutions,” Metallofiz. Noveish. Tekhnol. 33(3), 331–345 (2011).

    CAS  Google Scholar 

  19. P. V. Petrenko, N. P. Kulish, N. A. Mel’nikova, and Yu. E. Grabovskii, “Anomalous changes in the residual resistivity of short-range ordered alloys upon irradiation,” Phys. Met. Metallogr. 85, 423–427 (1998).

    Google Scholar 

  20. Ya. V. Petrenko, N. A. Mel’nikova, N. P. Kulish, Yu. E. Grabovskni, A. L. Gritskevich, and I. V. Lebedeva, “Effect of electron irradiation on the character of short-range order in binary solid solutions,” Metallofiz. Noveish. Tekhnol. 21(11), 75–82 (1999).

    CAS  Google Scholar 

  21. W. Schüle, “Enhancement of diffusion due to irradiation,” Z. Naturforsch., A: Phys. Sci. 209, 527–532 (1965).

    Google Scholar 

  22. J. M. Williams, M. S. Wechsler, and J. M. Barrett, “2nd-run phenomenon in irradiated Cu-15 at % Al,” Bull. Am. Phys. Soc. 8(3–5), 197 (1963).

    Google Scholar 

  23. N. P. Kulish, N. A. Mel’nikova, P. V. Petrenko, A. L. Ryabishchuk, and A. A. Tatarov, “Effect of electron irradiation on the short-range order of Cu-Al and Ag-Al alloys,” Fiz. Met. Metalloved., No. 12, 81–85 (1990).

    Google Scholar 

  24. O. M. Barabash and Yu. N. Koval’, Crystal Structure of Metals and Alloys. A Handbook (Naukova Dumka, Kiev, 1986) [in Russian].

    Google Scholar 

  25. C. R. Houska and B. L. Averbach, “Neutron irradiation effect in a Copper-Aluminium Alloy,” J. Appl. Phys. 30, 1525–1531 (1959).

    Article  CAS  Google Scholar 

  26. V. M. Andronov, I. G. Ivanov, A. F. Sirenko, and V. A. Sherstyuk, “Oscillating character of the property-composition dependences of metallic solutions,” Vopr. At. Nauki Tekh.: Fiz. Radiats. Povrezhd. Radiats. Materialoved., No. 2 (40), 83–87 (1987).

    Google Scholar 

  27. Yu. I. Ustinshchikov, “Ordering and Separation in Phase Diagrams,” Russ. Metall. (Metally), No. 3, 249–258 (2007).

    Google Scholar 

  28. V. I. Arkharov, “Fine character of physical phenomena in solids and the necessity of refinement of concepts concerning their mechanisms,” Fiz. Tverd. Tela, Respubl. Mezhvedomstv. Nauchn.-Tekh. Sb (Osnova, Donetsk, 1990), no. 20, pp.4–13.

    Google Scholar 

  29. G. Thomas, “Some applications of transmission electron microscopy to phase transformations,” in Diffraction and Imaging Techniques in Material Science, Ed. by S. Amelinckx, R. Gevers, and J. van Landuyt, 2nd ed. (North Holland, Amsterdam, 1978; Metallurgiya, Moscow, 1980), pp. 217–249.

    Chapter  Google Scholar 

  30. W. Gaudig and H. Warlimont, “Direct Beobachtungen des Nahordnungszustandes und einer stabilen überstructurphas in α-Kupfer-Aluminium Legierungen,” Z. Metallk. 60, 488–498 (1969).

    CAS  Google Scholar 

  31. P. V. Petrenko, N. P. Kulish, N. A. Mel’nikova, and Yu. E. Grabovskii, “Mechanisms of low-temperature recovery of Cu-Al solid solutions deformed at liquidnitrogen temperature,” Metallofiz. Noveish. Tekhnol. 34(1), 37–50 (2012).

    CAS  Google Scholar 

  32. J. M. Roland, A. Quillard, and S. K. Marya, “On the kinetics of α-phase ordering in copper-aluminum alloys,” Phys. Status Solidi A 66, 347–360 (1981).

    Article  CAS  Google Scholar 

  33. W. Pearson, The Crystal Chemistry and Physics of Metals and Alloys (New York: Wiley, 1972; Mir, Moscow, 1977).

    Google Scholar 

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Correspondence to Yu. E. Grabovskii.

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Original Russian Text © P.V. Petrenko, N.P. Kulish, N.A. Mel’nikova, Yu.E. Grabovskii, 2013, published in Fizika Metallov i Metallovedenie, 2013, Vol. 114, No. 12, pp. 1092–1100.

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Petrenko, P.V., Kulish, N.P., Mel’nikova, N.A. et al. Physical nature of structural and phase transformations in Cu-Al α solid solutions upon low-temperature irradiation and subsequent annealing. Phys. Metals Metallogr. 114, 1009–1017 (2013). https://doi.org/10.1134/S0031918X13120053

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  • DOI: https://doi.org/10.1134/S0031918X13120053

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